Results 81 to 90 of about 8,448 (204)

Electrochemical treatment of industrial sulfidic spent caustic streams for sulfide removal and caustic recovery

open access: yes, 2020
Alkaline spent caustic streams (SCS) produced in the petrochemical and chemical manufacturing industry, contain high concentrations of reactive sulfide (HS-) and caustic soda (NaOH).
Fiset, Erika   +4 more
core   +2 more sources

Rate-limiting step analysis of the microbial desulfurization of dibenzothiophene in a model oil system [PDF]

open access: yes, 2013
A mechanistic analysis of the various mass transport and kinetic steps in the microbial desulfurization of dibenzothiophene (DBT) by Rhodococcus erythropolis IGTS8 in a model biphasic (oil–water), small-scale system was performed.
Abin-Fuentes, Andres   +4 more
core   +1 more source

Structural and Electrochemical Evolution of Nickel Sulfides During Alkaline Hydrogen Evolution Reaction

open access: yesChemSusChem, EarlyView.
Post‐HER surface restructuring of nickel Sulfides (NixSy) through Sulfur leaching results in the formation of catalytically active Ni3S2, the most HER‐active nickel sulphide phase. The electrochemical activation process enhances hydrogen evolution performance while exhibiting self‐limiting behavior, ensuring long‐term catalyst stability in alkaline ...
Sina Haghverdi Khamene   +3 more
wiley   +1 more source

Transannular O‐Heterocyclization Reactions of Cyclododeca‐1,5,9‐triene Derivatives: A New Concept for the Preparation of Key Intermediates for Total Syntheses of Annonaceous Acetogenins

open access: yesHelvetica Chimica Acta, EarlyView.
Four stereogenic centers are formed diastereoselectively in one step from a cyclic (E,E)‐1,5‐diene system using an electrophilic addition reaction. Subsequent ozonolytic cleavage of the intact Z‐double bond, followed by intramolecular nucleophilic substitution, yields an octahydroterfurandione with a threo,cis,threo configuration, an arrangement found ...
Holger Schimanski   +6 more
wiley   +1 more source

Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes

open access: yesJournal of Engineering, 2015
Two different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD) sour crude oil (3.9wt% sulfur content).
Neran Khalel Ibrahim, Prof. Dr.   +1 more
doaj   +2 more sources

Optimal Design and Operation of an Industrial Three Phase Reactor for the Oxidation of Phenol [PDF]

open access: yes, 2016
YesAmong several treatment methods Catalytic Wet Air Oxidation (CWAO) treatment is considered as a useful and powerful method for removing phenol from waste waters. In this work, mathematical model of a trickle bed reactor (TBR) undergoing CWAO of phenol
Awad, E.M.   +3 more
core   +1 more source

Intensification of diesel oxidative desulfurization via hydrodynamic cavitation

open access: yesUltrasonics Sonochemistry, 2019
A Hydrodynamic Cavitation Assisted Oxidative Desulfurization (HCAOD) process was applied for treatment of diesel fuel feedstock using hydrogen peroxide and formic acid as the oxidant and catalyst, respectively. Investigation on the effect of main process variables including pressure drop (3-6 bar), time of treatment (10-30 min) and formic acid to ...
Soroush, Baradaran   +1 more
openaire   +2 more sources

Sulfur Ylides in Skeletal‐Editing—Ring Expansion Reactions

open access: yesHelvetica Chimica Acta, EarlyView.
Sulfur ylides (S‐ylides) are emergent diazo surrogates that enable skeletal editing and ring expansion with safer handling and broad functional group tolerance. This perspective covers pioneer works and highlights recent advances in the field, while outlining key challenges and future directions that may redefine the role of S‐ylides in modern ...
Arsala Kamal   +3 more
wiley   +1 more source

Rapid Total Synthesis of DARPin pE59 and Barnase [PDF]

open access: yes, 2013
We report the convergent total synthesis of two proteins: DARPin pE59 and Bacillus amyloliquefaciens RNase (Barnase). Leveraging our recently developed fast-flow peptide-synthesis platform, we rapidly explored numerous conditions for the assembly of long
Mong, Surin Khai   +3 more
core   +1 more source

The Application of Hydrochar Composite Briquettes for Sustainable Slag Foaming in the Electric Arc Furnace Process

open access: yessteel research international, EarlyView.
Hydrochar‐mill‐scale briquettes with varying C/O molar ratios (0.07–0.90) have been tested at 1650 °C to evaluate their slag foaming performance for electric arc furnace application. All seven briquette recipes developed succeed in promoting slag foaming.
Yu‐Chiao Lu   +3 more
wiley   +1 more source

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