Results 171 to 180 of about 4,052,823 (334)

Oxygen Isotope Alterations during the Reduction of U3O8 to UO2 for Nuclear Forensics Applications. [PDF]

open access: yesACS Omega, 2023
Assulin M   +6 more
europepmc   +1 more source

Beyond Formate Trapping: A Mechanistic Framework for Homogeneous CO2‐to‐Methanol Conversion With First‐Row Transition Metals

open access: yesAngewandte Chemie, EarlyView.
This review shows that converting CO2 into methanol with catalysts based on abundant first‐row metals requires more than overcoming formate formation. Success depends on balancing hydrogen activation, intermediate reactivity, product release, and catalyst stability.
Elise Boudry, Christophe M. Thomas
wiley   +2 more sources

Configurational Entropy and Compositional Effects in Fe‐Based Oxide 2D Sheets for Nitrate Electroreduction

open access: yesAdvanced Energy Materials, EarlyView.
FeCuCoMnZnOx integrates diverse heteroatomic bridge‐site environments and composition‐dependent electronic structures to promote nitrate activation and sequential hydrogenation toward ammonia, demonstrating that nitrate reduction reaction performance is governed by the combined effects of composition and local coordination rather than configurational ...
Muhammad Usman   +14 more
wiley   +1 more source

Unveiling the Complete Biosynthetic Pathway of Azacitidine: A Rare 1,3,5‐Triazine Nucleoside Derived From GTP

open access: yesAngewandte Chemie, EarlyView.
The azacitidine biosynthetic gene cluster (aza BGC) was identified by the resistance‐gene‐guided comparative genomics method in Streptomyces mobaraensis IPIO2. The complete biosynthetic pathway of azacitidine, which follows a “base‐first‐then‐glycosylation” logic, was elucidated through in vivo and in vitro experiments.
Dan Wang   +6 more
wiley   +2 more sources

Chloride‐Mediated Activation of Aluminum‐Alloyed Liquid Metal Anodes for Stretchable Asymmetric Energy Storage

open access: yesAdvanced Energy Materials, EarlyView.
A gallium‐centered cell pairs an aluminum‐alloyed GaIn anode with a GaOOH cathode in a chloride‐rich water‐in‐ionic‐liquid electrolyte. Chlorogallate ions dissolve the native oxide that normally seals the liquid metal, and preferentially reduce indium seeds to oxide‐free clusters on which gallium plates and strips reversibly.
Adit Gupta   +3 more
wiley   +1 more source

Advancing annually resolved oxygen isotope dendrochronology to overcome wood-dating limitations in the Euro-Atlantic region. [PDF]

open access: yesPLoS One
Rodríguez-Morata C   +7 more
europepmc   +1 more source

Guest Transition Metals in Host Keplerate Nanocapsules as Supramolecular Inorganic Functional Mimics of Monooxygenase Enzymes

open access: yesAngewandte Chemie, EarlyView.
A Keplerate, an inorganic, porous buckyball was used as a host for copper metal cations ligated by histidine surrogates. Prepared by a simple assembly technique, the guest–host complex was used as a primitive biomimetic model of a monooxygenase enzyme complex, where C─H bonds were electrocatalytically hydroxylated by oxygen under reducing conditions ...
Eynat Haviv   +4 more
wiley   +2 more sources

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