Results 151 to 160 of about 139,618 (290)

In Situ Measurement of Oxygen Vacancy Dynamics and Surface Exchange Reactions in Oxide Electrode under Solid Electrochemical Cell Operating Conditions

open access: yesAdvanced Energy Materials, EarlyView.
This study establishes an in situ electrochemical framework using dense bulk electrodes to identify defect chemistry and surface kinetics. While oxygen vacancy concentration is derived via bias modulation, surface exchange coefficients are quantified at open circuit voltage conditions to isolate kinetics.
Taeyun Kim   +5 more
wiley   +1 more source

Strontium and oxygen isotopes to trace mobility routes during the Bell Beaker period in the north of Spain. [PDF]

open access: yesSci Rep, 2021
Ortega LA   +5 more
europepmc   +1 more source

Main‐Chain Ion‐Pair Polybenzimidazole Membranes Enabling Reduced‐Temperature HT‐PEMFC Operation (Down to 120°C)

open access: yesAdvanced Energy Materials, EarlyView.
Embedding imidazolium‐biphosphate ion pairs directly into the polybenzimidazole main chain simultaneously stabilizes phosphoric acid and preserves continuous proton transport pathways. Strong ion‐pair and hydrogen‐bond interactions suppress acid leaching while maintaining high conductivity, enabling stable and durable high‐temperature fuel cell ...
Huina Lin, Brian C. Benicewicz
wiley   +1 more source

A Homogeneously Catalyzed Paired Electrolytic Cell for Hydrogen Peroxide Production

open access: yesAngewandte Chemie, EarlyView.
Cu(tmpa) and Sn‐TMPyP are compatible and efficient catalysts for 2e−‐ORR and 2e−‐WOR, respectively, which have been employed to assemble an efficient paired electrochemical cell for H2O2 production. The presence of a carbonate buffer is essential to achieve a high activity in the anode compartment, while control over mass transport is essential for a ...
Caterina Trotta   +7 more
wiley   +2 more sources

Reply to Weiss: Tree-ring stable oxygen isotopes suggest an increase in Asian monsoon rainfall at 4.2 ka BP. [PDF]

open access: yesProc Natl Acad Sci U S A, 2022
Yang B   +20 more
europepmc   +1 more source

Topology‐Aware Machine Learning for High‐Throughput Screening of MOFs in C8 Aromatic Separation

open access: yesAdvanced Intelligent Discovery, EarlyView.
We screened 15,335 Computation‐Ready, Experimental Metal–Organic Frameworks (CoRE‐MOFs) using a topology‐aware machine learning (ML) model that integrates structural, chemical, pore‐size, and topological descriptors. Top‐performing MOFs exhibit aromatic‐enriched cavities and open metal sites that enable π–π and C–H···π interactions, serving as ...
Yu Li, Honglin Li, Jialu Li, Wan‐Lu Li
wiley   +1 more source

Crystals as Rockets: Modulation of the Salient Temperature in Cocrystals by Solvent Mixture Composition

open access: yesAngewandte Chemie, EarlyView.
Compositionally engineered mixed solvated cocrystals enable modulation of thermosalient actuation. Guest ratio controls thermosalient temperature and propulsion intensity, providing a tunable platform for designing crystalline systems that exhibit stimuli‐responsive mechanical motion.
Ernesto A. Hernández‐Morales   +5 more
wiley   +2 more sources

Tree-ring oxygen isotopes record a decrease in Amazon dry season rainfall over the past 40 years. [PDF]

open access: yesClim Dyn, 2022
Cintra BBL   +7 more
europepmc   +1 more source

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

open access: yesAdvanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source

Acceptorless Dehydrogenative Polymerization

open access: yesAngewandte Chemie, EarlyView.
Acceptor‐less dehydrogenative polymerization (ADP) enables the atom‐economic step‐growth synthesis of different type of polymers directly from simple alcohols, releasing H2 as the sole by‐product. This review outlines the mechanistic foundations, catalytic systems, and emerging polymer architectures of ADP, highlighting its potential as a sustainable ...
Xin Liu   +2 more
wiley   +2 more sources

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