Results 171 to 180 of about 37,366 (283)

Factors Influencing the Oxygen Isotopes of Grape Berry Water: Some Remarks. [PDF]

open access: yesInt J Food Sci
Rossi M   +5 more
europepmc   +1 more source

Garnet secondary ion mass spectrometry oxygen isotopes reveal crucial roles of pulsed magmatic fluid and its mixing with meteoric water in lode gold genesis. [PDF]

open access: yesProc Natl Acad Sci U S A, 2022
Fan GH   +12 more
europepmc   +1 more source

Catalytic Enantioselective Multicomponent Reactions of Sulfoxonium Ylides Enabled by a Formal Rearrangement—A Versatile Entry to Enantioenriched α‐Sulfanyl Carbonyl Compounds

open access: yesAngewandte Chemie, EarlyView.
A catalytic network embedding a formal rearrangement enables the first catalytic enantioselective multicomponent reaction (MCR) of sulfur ylides. In the presence of a bulky chiral phosphoric acid, the reaction combines sulfoxonium ylides, aldehydes and thiols, and affords synthetically versatile β‐hydroxy‐α‐sulfanyl carbonyl compounds in ...
Nicolò Santarelli   +10 more
wiley   +2 more sources

Bifurcation of *COOH Pathway Determines HCOOH Formation in CO2 Electroreduction on Bismuth

open access: yesAngewandte Chemie, EarlyView.
Driven by the mechanistic debate of Bi‐catalyzed CO2‐to‐HCOOH conversion, ambiguity remains regarding true reaction pathways. To resolve this, we combined constant‐potential AIMD simulations with spectroscopic evidence to analyze the competitive pathways.
Hyun Dong Jung   +4 more
wiley   +2 more sources

Facet‐Dependent Water Inhibition of Alkanol Dehydration on TiO2 via Distinct Water–Alkanol Complexes

open access: yesAngewandte Chemie, EarlyView.
Water inhibits alkanol dehydration on TiO2 through facet‐dependent manners via distinct IPA‐water complexes. On TiO2(001), water forms a strongly hydrogen‐bonded isopropoxide–H2O complex that readily dominates the surface and substantially elevates the activation barrier, whereas on TiO2(101), water weakly hydrogen‐bonds to molecular IPA, resulting in ...
Wenda Hu   +14 more
wiley   +2 more sources

Graphdiyne as a Hole‐Transport Channel in Carbon Nitride Heterojunctions for Synergistic CO2 Reduction and γ‐Butyrolactone Synthesis

open access: yesAngewandte Chemie, EarlyView.
A fully metal‐free heterojunction constructed from graphdiyne (GDY) and polymeric carbon nitride (PCN) enables efficient coupling of CO2 reduction and tetrahydrofuran oxidation. GDY serves as a hole‐transport channel, establishing a built‐in electric field that drives spatial charge separation. The optimized catalyst achieves near‐unity selectivity for
Xuan Zhang   +7 more
wiley   +2 more sources

Mass-independent fractionation of oxygen isotopes during high-temperature condensation in cosmochemical plasmas. [PDF]

open access: yesProc Natl Acad Sci U S A
Asset N   +6 more
europepmc   +1 more source

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