Results 191 to 200 of about 37,366 (283)

Strontium and oxygen isotopes as indicators of Longobards mobility in Italy: an investigation at Povegliano Veronese. [PDF]

open access: yesSci Rep, 2020
Francisci G   +8 more
europepmc   +1 more source

Single‐Atom Iron‐Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin‐Derived Feedstocks

open access: yesAngewandte Chemie, EarlyView.
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma   +8 more
wiley   +2 more sources

Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration

open access: yesAngewandte Chemie, EarlyView.
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti   +9 more
wiley   +2 more sources

Strain Engineering via W–O–Ru Interfacial Coupling to Suppress Lattice Oxygen Activation for Stable Acidic Water Electrolysis

open access: yesAngewandte Chemie, EarlyView.
Constructing atomically coupled W–O–Ru interfacial units on RuO2 triggers a dynamic strain evolution during the oxygen evolution reaction. An initial tensile strain secures structural stability, while a self‐adjusting transition to interfacial compression optimizes catalytic activity.
Yi Guan   +7 more
wiley   +2 more sources

Oxygen isotopes in orangutan teeth reveal recent and ancient climate variation. [PDF]

open access: yesElife
Smith TM   +11 more
europepmc   +1 more source

Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes

open access: yesAngewandte Chemie, EarlyView.
A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi   +7 more
wiley   +2 more sources

The Maya Are a People of Movement: Reconstructing Shifts in Maya Mobility From Oxygen Isotopes Across Three Millenia at Santa Rita Corozal (Chactemal), Northern Belize. [PDF]

open access: yesAm J Biol Anthropol
Locker AJ   +11 more
europepmc   +1 more source

Recent benthic foraminifera from the Tagus Prodelta and Estuary, Portugal: microhabitats, assemblage composition and stable isotopes [PDF]

open access: yes, 2006
Bartels-Jónsdóttir, Helga Bára   +4 more
core   +1 more source

Quantitative Photo‐Reforming of Biomass to CO Spurred by In Situ Protonation of Carbon Dioxide Radical Anions

open access: yesAngewandte Chemie, EarlyView.
A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu   +5 more
wiley   +2 more sources

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