Covalent Attachment of a Platinum(II) Complex inside DNA Duplexes
ChemistryEurope, EarlyView.Oxidative addition is used for the site‐specific incorporation of an organometallic PtII complex as an artificial nucleobase into a DNA duplex. The platination stabilizes the duplex and confers it with phosphorescence. An organometallic phosphorescent PtII complex is introduced into DNA duplexes via oxidative addition to a tailor‐made artificial ...
Tim Schäfer +6 more
wiley +1 more source
Enhancing the d–Electrocatalytic Activity of MXene Through Defect Engineering
Carbon Energy, EarlyView.Applications of MXene. ABSTRACT Due to their versatile and tunable surface and bulk chemistry, MXenes have great potential as electrocatalysts for batteries and supercapacitors. When compared with other electrocatalytic processes, in electrocatalytic reactions, MXenes could improve ion diffusion and charge transfer by either providing functional groups
Chenxue Wang +4 more
wiley +1 more source
Regulating Defect‐Coordinated Single‐Iron‐Atom Catalysts for Efficient Nitrate Reduction Reactions
Carbon Energy, EarlyView.This figure illustrates the ball‐and‐stick model of an asymmetric monatomic Fe─N2 catalyst and its catalytic process for converting nitrate to ammonia. Shown are the adsorption configurations of precursors and intermediates (NO3− → NO2− → NO → NH2OH → NH3) on the catalyst surface, where brown represents iron atoms, red represents oxygen atoms, dark ...
Xia Ma +12 more
wiley +1 more source
Mechanism of methylphosphonic acid photo-degradation based on phosphate oxygen isotopes and density functional theory. [PDF]
RSC Adv, 2019 Xia C +9 more
europepmc +1 more source
Asymmetric‐Coordinated Indium Single Atoms for Highly Selective Photocatalytic CO2 Reduction
Carbon Energy, EarlyView.This work develops an indium single‐atom photocatalyst (In‐NTO) featuring unique Inδ⁺–N3O2 coordination sites for highly selective CO2 photoreduction. The specific atomic interface steers the reaction pathway exclusively toward CO (95.9% selectivity) by lowering the overall energy barrier and converting the critical *CO protonation step from ...
Fengyu Tian +6 more
wiley +1 more source
Flows of people in villages and large centres in Bronze Age Italy through strontium and oxygen isotopes. [PDF]
PLoS One, 2019 Cavazzuti C +7 more
europepmc +1 more source
Interfacial Ru–O–W Orbital Coupling Enables Lattice Oxygen Stabilization for Enhanced Acidic OER
Carbon Energy, EarlyView.A RuO2/WO3 electrocatalyst with strong interfacial Ru–O–W bonds exhibits optimized Ru–O interactions, enhancing intrinsic activity and stability for acidic OER. The WO3 support modulates the electronic structure of RuO2 and promotes oxo‐intermediate deprotonation, delivering a low overpotential of 203 mV at 10 mA cm−2 and sustained operation beyond 200
Tongzhou Wang +9 more
wiley +1 more source
Functionalizing Conductive Diamond: Recent Advance in Fabrication, Modifications, and Applications
Carbon Energy, EarlyView.This review highlights recent advancements in the synthesis, modification, and electrochemical applications of conductive diamond, particularly boron‐doped diamond (BDD). It emphasizes progress in fabrication methods, including CVD and HPHT, and explores modifications such as doping, surface terminations, and composite design, enabling significant ...
Ning Linghu, Xin Jiang, Jing Xu
wiley +1 more source
Tooth oxygen isotopes reveal Late Bronze Age origin of Mediterranean fish aquaculture and trade. [PDF]
Sci Rep, 2018 Guy SV +7 more
europepmc +1 more source
Carbon Energy, EarlyView.Zhao et al. control the coverage of *CO or *H intermediates by introducing foreign metal into Cu nanoparticles. The increased *CO coverage on Ag‐doped and Zn‐doped Cu promotes the generation of multi‐carbon products while the increased *H coverage of Co‐doped and Pd‐doped Cu enhances the selectivity of oxygenates. ABSTRACT As key reaction intermediates
Zi‐Hao Zhao +3 more
wiley +1 more source