Results 161 to 170 of about 347,511 (234)

Routes to Pt Derivatives of High‐Valent Sulfur Oxofluorides S(═O)2F, S(═O)F2, and S(═O)F3 by Fluorination and Oxygenation

open access: yesAngewandte Chemie, EarlyView.
This study demonstrates the controlled functionalization of a SOF ligand at a platinum center, achieving the selective formation of SO2F and SOF2 complexes by fluorination or oxygenation. Further fluorination of the SOF2 ligand resulted in an unprecedented SOF3 metal derivative, which is a unique example of a high‐valent fluorinated sulfur atom ...
Ruben Jaeger   +5 more
wiley   +2 more sources

Pangenome Analysis of the Plant Pathogen Pseudomonas syringae Reveals Unique Natural Products for Niche Adaptation

open access: yesAngewandte Chemie, EarlyView.
A pangenome analysis of the plant pathogen Pseudomonas syringae reveals two novel natural product families that facilitate niche adaptation. Comprehensive genomic and chemical analyses uncover unique biosynthetic gene clusters linked to host specificity and environmental fitness.
Shuaibing Zhang   +7 more
wiley   +2 more sources

Hydrogen Atom Transfer-Based C(sp<sup>3</sup>)-H Bond Oxygenation of Lactams and Cycloalkenes: The Influence of Ring Size on Reactivity and Site Selectivity. [PDF]

open access: yesJ Org Chem
Sisti S   +9 more
europepmc   +1 more source

Structural Basis of Sequential Enantioselective Epoxidation by a Flavin‐Dependent Monooxygenase in Lasalocid A Biosynthesis

open access: yesAngewandte Chemie, EarlyView.
Lsd18 is a flavin‐dependent monooxygenase from Streptomyces lasalocidi that performs two enantioselective epoxidations during lasalocid A biosynthesis. X‐ray crystal structures of Lsd18 bound to a substrate and product analogue illuminate how this enzyme performs multiple epoxidations on the same substrate molecule and how it controls stereoselectivity.
Qian Wang   +12 more
wiley   +2 more sources

Cathodic Hydroxide Ions Induce Tetrose Formation during Glycolaldehyde Electroreduction to Alcohols: A Potential CO2‐to‐Carbohydrate Pathway

open access: yesAngewandte Chemie, EarlyView.
The glycolaldehyde electrolysis mechanism to alcohols and tetroses is comprehensively studied. Novel insights on the role of glycolaldehyde in the late stages of the overall CO2 reduction reaction pathways to ethanol and ethylene glycol on copper are presented.
Ernest Pahuyo Delmo   +12 more
wiley   +2 more sources

Apnoeic oxygenation in pediatric anesthesia: better safe than sorry! [PDF]

open access: yesBMC Anesthesiol
Uzun DD   +4 more
europepmc   +1 more source

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