A Crystalline Ylide‐Stabilized Stibenium Cation
The isolation of a stibenium cation stabilized by two thiophosphinoyl‐tethered ylide groups is reported. The cation is accessible via salt metathesis of the metalated ylide with SbCl3 and features CSb single bonds, with lone pairs remaining localized at the ylidic carbon atoms.
Daniel Knyszek +4 more
wiley +1 more source
FeCu dual-single-atom catalyst promotes gradient H<sub>2</sub>O<sub>2</sub> activation for enhanced methane oxidation to methanol. [PDF]
Zhang H +13 more
europepmc +1 more source
Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley +1 more source
Smallest acyclic tricationic molecule containing a Bis(phosphine)-stabilized low-valent triantimony-based Unit. [PDF]
Mukherjee N +13 more
europepmc +1 more source
Ligand‐Level Chemical Activation: Coordination with Benefits
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier +2 more
wiley +1 more source
Inactivated Avian Infectious Bronchitis Virus Strains M41 and 4-91 Provide Broad Protection Against Multiple Avian Infectious Bronchitis Strains. [PDF]
van de Weem NMP +7 more
europepmc +1 more source
Mechanical stability in flexible perovskite solar cells: Interface engineering and device design
Statistics of the improvement methods for f‐PSCs. Abstract Flexible perovskite solar cells (f‐PSCs) demonstrate significant potential for application in next‐generation wearable electronic devices and photovoltaic building integration due to their high power conversion efficiency and excellent power‐to‐weight ratio. However, the inherent brittleness of
Hong‐Yi Hou +3 more
wiley +1 more source
Circulating genotypes of human papillomavirus in adult women of reproductive age from the Boeny region of Madagascar: a cross-sectional study to explore needs and opportunities for HPV vaccination in the country. [PDF]
Garsevanidze E +25 more
europepmc +1 more source
NOTES ON GENERALIZED INTEGRAL OPERATOR INCLUDES PRODUCT OF p-VALENT MEROMORPHIC FUNCTIONS [PDF]
DARUS, MASLINA, MOHAMMED, AABED
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