Results 191 to 200 of about 24,023,096 (279)

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

open access: yesAngewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu   +3 more
wiley   +2 more sources

Substrate‐Dependent Crosslinking by the Cytochrome P450 From Aminopyruvatide Biosynthesis

open access: yesAngewandte Chemie, EarlyView.
Substitutions in the aminopyruvatide precursor peptide altered the C─C linkage formed from a YLY motif by the P450 ApyO to a N─C linkage in a WLY motif. Moreover, constitutional isomers crosslinked by C─C and C─O linkages were formed from YYY or YWY motifs. ABSTRACT Cytochrome P450s catalyze an array of reactions including crosslinking of aromatic side
Chandrashekhar Padhi   +6 more
wiley   +2 more sources

Nasopharyngeal carriage of Streptococcus pneumoniae in children aged two to five years old in the conjugate vaccine era: A cross-sectional study in Salvador, Brazil. [PDF]

open access: yesPLoS One
Sousa IO   +10 more
europepmc   +1 more source

1,4‐Brook Rearrangement of β‐Silyl Allylic Alcohols: Trisubstituted Alkenes by Copper‐Mediated Stereoretentive ipso‐Substitution Reactions

open access: yesAngewandte Chemie, EarlyView.
To fully leverage the power of the ruthenium‐catalyzed trans‐hydrosilylation of propargyl alcohols, it was necessary to develop a practical and robust method for the activation of those products that carry the silyl group distal to the hydroxy substituent.
Paul Haf‐Moths   +2 more
wiley   +2 more sources

Adjuvant human papillomavirus vaccination after excisional treatment for cervical precancer. [PDF]

open access: yesTurk J Obstet Gynecol
Özen S   +4 more
europepmc   +1 more source

Decouple H2O2 Electrosynthesis From Microenvironmental Decomposition via Atomic Site Density Engineering

open access: yesAngewandte Chemie, EarlyView.
Using defect‐rich Co‐N2O2 single‐atom catalysts as a model system, this work reveals that atomic site density governs the competition between H2O2 electrosynthesis and microenvironmental decomposition during 2e−‐ORR. Optimised site isolation suppresses HPRR and HDR, thereby establishing a site‐density principle to balance H2O2 formation and ...
Junwen Chen   +8 more
wiley   +2 more sources

Trends and cross-county disparities in childhood pneumococcal vaccination in Zhejiang Province, China, 2011-2022. [PDF]

open access: yesBMC Health Serv Res
Wang Y   +8 more
europepmc   +1 more source

Home - About - Disclaimer - Privacy