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Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
Angewandte Chemie - International Edition, 2009 In the past decade, palladium-catalyzed C-H activation/C-C bond-forming reactions have emerged as promising new catalytic transformations; however, development in this field is still at an early stage compared to the state of the art in cross-coupling ...
Dong-hui Wang +2 more
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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
Chemical Reviews, 2010 1.1 Introduction to Pd-catalyzed directed C–H functionalization The development of methods for the direct conversion of carbon–hydrogen bonds into carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds remains a critical ...
Melanie S Sanford
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DOUBLE BROMIDES OF PALLADIUM. [PDF]
Journal of the American Chemical Society, 1894 n ...
Edgar F. Smith, Daniel L. Wallace
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Nature Communications, 2022 Development of reversible and stable catalysts for the electrochemical reduction of CO 2 is of great interest. Here, we elucidate the atomistic details of how a palladium electrocatalyst inhibits CO poisoning during both formic acid oxidation to carbon ...
Xiaoting Chen +3 more
semanticscholar +1 more source
Investigation by STEM-EELS of helium density in nanobubbles formed in aged palladium tritides [PDF]
J. Alloys Compd., 878 (2021) 160267, 2021 3He nanobubbles created by radioactive decay of tritium in palladium tritide are investigated after several years of aging. Scanning Transmission Electron Microscopy Electron Energy-Loss Spectroscopy (STEM-EELS) has been used to measure helium density from the helium K-edge around 23 eV. Helium densities were found between 20 and 140 (+/-30) He/nm3 and
arxiv +1 more source
Resistivity testing of palladium dilution limits in CoPd alloys for hydrogen storage [PDF]
Materials 15, 111 (2022), 2022 Palladium satisfies most of the requirements for an effective hydrogen storage material with two major drawbacks: it has a relatively low gravimetric hydrogen density and is prohibitively expensive for large-scale applications. Pd-based alloys should be considered as possible alternatives to a pure Pd.
arxiv +1 more source
$L$-hole Pockets of the Palladium Fermi Surface Revealed by Positron Annihilation Spectroscopy [PDF]
, 2021 Using the combined Density Functional and Dynamical Mean Field theory we study relativistic corrections to the Fermi surface of palladium. We find indeed that relativistic corrections create a small hole pockets at the $L$-symmetry points. Furthermore we show that the computed two dimensional Angular Correlation of Electron Positron Annihilation ...
arxiv +1 more source
Angewandte Chemie, 2019 A (terpy)Pd/NHC cooperative catalyzed umpolung 1,4-addition of aryl iodides to enals to generate various bioactive β,β-diaryl propanoate derivatives is described.
Wenjun Yang +5 more
semanticscholar +1 more source
Emergence of magnetism in bulk amorphous palladium [PDF]
Phys. Rev. B 100, 024422 (2019), 2019 Magnetism in palladium has been the subject of much work and speculation. Bulk crystalline palladium is paramagnetic with a high magnetic susceptibility. Palladium under pressure and palladium nanoclusters have generated interest to scrutinize its magnetic properties.
arxiv +1 more source
Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
, 1995 B. Other Catalyti; Process by Transition-Metal Complexes IV. Cross-Coupling Reaction A. Coupling of 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6. Coupling of Arylboron Derivatives: Synthesis of Biaryls C.
N. Miyaura, A. Suzuki
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