Results 91 to 100 of about 1,722,857 (346)

Reações de hidrogenação e isomerização de olefinas utilizando nanopartículas de paládio estabilizadas por um surfactante dipolar iônico baseado no anel imidazol [PDF]

open access: yes, 2014
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-graduação em Química, Florianópolis, 2014O presente trabalho descreve a preparação de dois catalisadores baseados em nanopartículas
Leopoldino, Elder Correa
core  

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

open access: yesAdvanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang   +4 more
wiley   +1 more source

Dehydrogenation of Ethylene on Supported Palladium Nanoparticles: A Double View from Metal and Hydrocarbon Sides

open access: yesNanomaterials, 2020
Adsorption of ethylene on palladium, a key step in various catalytic reactions, may result in a variety of surface-adsorbed species and formation of palladium carbides, especially under industrially relevant pressures and temperatures.
Oleg A. Usoltsev   +8 more
doaj   +1 more source

Nanocatalisadores metálicos de paládio e prata estabilizados com novos líquidos iônicos piridínicos para aplicação em reações de Heck e redução [PDF]

open access: yes, 2015
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2015.Este trabalho foi dividido em: (i) síntese de novos líquidos iônicos (LIs) piridínicos para ...
Signori, Aline Maria
core  

Palladium-Catalyzed Tandem Isomerization/Hydrothiolation of Allylarenes

open access: yes, 2019
Herein we report a tandem olefin migration/hydrothiolation of allyl benzenes facilitated by an in situ generated palladium hydride. A catalyst system composed of palladium acetate and bidentate ligand dtbpx (1,2-bis­(di-tert-butyl­phosphino­methyl ...
Prasad M. Kathe (6457784)   +1 more
core   +1 more source

Recent Progress in the Phase‐Controlled Synthesis of Ruthenium Nanocrystals for Catalytic Applications

open access: yesAdvanced Materials, EarlyView.
Template effect and kinetic control enable crystal‐phase engineering of Ru nanocrystals, granting access to either metastable fcc‐Ru or stable hcp‐Ru with distinct surface structures, thermal stabilities, and catalytic behaviors. Moreover, the hcp‐Ru can further serve as an epitaxial template to direct Pd and Rh nanocrystals into the metastable hcp ...
Jianlong He   +3 more
wiley   +1 more source

Green synthesis of palladium nanoparticles using gum ghatti (Anogeissus latifolia) and its application as an antioxidant and catalyst

open access: yesArabian Journal of Chemistry, 2015
A facile and green route for the synthesis of palladium nanoparticles from palladium chloride was developed using non-toxic, renewable plant polymer, gum ghatti ( Anogeissus latifolia ), as both the reducing and stabilizing agent.
Aruna Jyothi Kora, L. Rastogi
semanticscholar   +1 more source

Palladium-Catalyzed Dimerization of Vinyl Ethers: Mechanism, Catalyst Optimization, and Polymerization Applications

open access: yes, 2019
The electron-rich nature of vinyl ethers (CH2CHOR) enables their versatile reactivity patterns with transition metal catalysts. Furthermore, they are highly attractive monomers for the synthesis of many polymers and copolymers.
Changwen Hong (7381388)   +2 more
core   +1 more source

Palladium-Catalyzed Carbonylation of Aryl Bromides with Carbon Dioxide To Access Aryl Carboxylic Acids under Mild Conditions

open access: yes, 2022
A palladium-catalyzed direct carbonylation of aryl bromides with carbon dioxide as the carbonyl source has been developed by using Pd(dba)2/DPEPhos as the catalyst under mild reaction conditions, providing an efficient route to a variety of aryl ...
Wenfang Xiong (1392916)   +5 more
core   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

open access: yesAdvanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen   +7 more
wiley   +1 more source

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