We developed a series of quinoxalinoquinoxaline (QQ) photosensitizers featuring high and tunable excited‐state reduction potentials (E(PC•+/PC*) = –1.76 to –2.05 V vs. SCE). Their hydrogen‐bonding interaction with carbonyl substrates enables selective single‐electron transfer events for selective nitrilization of 1° amides, offering a tunable ...
Seongwoo Bae, Dongwook Kim, Jinwoo Kim
wiley +1 more source
Nanoplastics and Neurodegeneration: A Roadmap From Mechanism to Causation
Nanoplastics are pervasive environmental contaminants with potentially profound implications for human health. Emerging evidence suggests a possible link between nanoplastic exposure and neurodegeneration, a key driver of ageing and dementia, yet causality remains unresolved.
Yuhuan Li +5 more
wiley +1 more source
Novel NHC-based Pd-PEPPSI complexes: synthesis, structural characterization by X-ray diffraction, biological properties, and catalytic performance in <i>N</i>-alkylation reactions. [PDF]
Boubakri L +8 more
europepmc +1 more source
Tensile‐strained bismuth nanosheets (TS‐BiNs) achieve a formate Faradaic efficiency of 92% at −1000 mA cm−2 and enable stable production of pure formic acid (HCOOH) in a solid‐state electrolyte reactor. Theoretical calculations reveal that the introduced strain lowers the energy barrier for *OCHO intermediate formation, fundamentally enhancing the ...
Shiqi Li +16 more
wiley +1 more source
Palladium [ <sup><i>t</i>‑Bu</sup>(PCP)PdOH] Pincer Complex as a Catalyst in the Michael Reaction. [PDF]
Urlep M, Lozinšek M, Cerkovnik J.
europepmc +1 more source
Reinforcing Oxygen Activation of Spinel Oxide via Mn─O Covalency Engineering for VOCs Oxidation
A MnCo spinel catalyst with weakened Mn─O covalency was synthesized via a hard‐template method. The reduced Mn─O covalency facilitates localized electron redistribution, promoting the activation of both molecular oxygen and lattice oxygen, and thereby enabling the efficient and complete oxidation of VOCs (ethyl acetate, toluene, and propane).
Gan Li +8 more
wiley +1 more source
Efficient Microwave-Assisted Palladium-Catalyzed Selective <i>N</i>-Arylation of Anilines with 2,3-Dihalopyridines in Water. [PDF]
Hu HC, Chen CY, Yang SC.
europepmc +1 more source
Atomic Interlayer Mo–N4 Sites Enable Rapid Charge Transfer and Efficient CO2 Photoreduction
This work achieved efficient CO2 activation and ultrafast interlayer electron transport in a 2D COF by constructing atomic‐level Mo‐N4‐induced interlayer electron bridges (IEB), thereby kinetically and thermodynamically co‐driving the photocatalytic coupling of CO2 reduction with 4‐methoxybenzyl alcohol oxidation.
Lijuan Sun +9 more
wiley +1 more source
Effect of palladium-doped magnetite nanoparticles in the hydrothermal liquefaction of biomass to bio-oil. [PDF]
Tumwebaze A, Mubiru E, Egesa D.
europepmc +1 more source

