Enantioselective Access to Trifluoromethylated Spirocyclopropyl Heterocycles
We report a rhodium‐catalyzed asymmetric [2+1] spirocyclopropanation of methylene azacycles with trifluoromethyl carbenes in situ derived from fluoroalkyl triftosylhydrazones. ABSTRACT Chiral spirocyclopropyl heterocycles have emerged as privileged three‐dimensional structural motifs in medicinal chemistry.
Yuanhao Zhu +9 more
wiley +1 more source
In situ ptychographic nanotomography captures activation, mobility, and deactivation of supported catalysts. [PDF]
Beck A +6 more
europepmc +1 more source
A scalable process converts para‐aramid fibers into soft‐magnetic building blocks via micrometer‐thick Fe0.64Ni0.36 (Invar‐type) coatings. Assembled into paper, they form a hierarchical conductive network whose tunable permeability enables thin, lightweight microwave absorption in the low‐frequency (S‐band) regime.
You Wu +7 more
wiley +1 more source
Metal-Catalyzed Reductive Coupling of Aryl Halides beyond Premetalated Reagents or Metallic Reductants: Biaryl Formation. [PDF]
Cho Y, Chang YH, Shen W, Krische MJ.
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Light‐Controlled Conductive Molecular Wire in an Artificial Lipid Membrane
A photochromic azobenzene derivative is shown to produce a unique photoelectric response when embedded in artificial lipid membranes. In its trans state, it forms conductive “molecular wires” that enhance membrane conductivity in the dark. Light‐induced cis isomerization suppresses this effect, showing that short‐chain molecules can modulate membrane ...
Ilaria Cardace +11 more
wiley +1 more source
Palladium-Catalyzed Fluoroallylation of Aldimine Esters With gem-Difluorocyclopropanes: Synthesis of Fluorinated α-Amino Acid Derivatives. [PDF]
Tang JW, Xu K, Su J, Chen Z, Lv L.
europepmc +1 more source
Description of the dataset on alkoxycarbonylation catalyzed by supported palladium phosphide nanoparticles. [PDF]
Neyyathala A +9 more
europepmc +1 more source
Dipyrromethane-diphosphines: nickel and palladium complexes as catalysts for the selective hydroboration of CO<sub>2</sub> to methoxyborane under mild conditions with mechanistic study. [PDF]
Gupta R, Kumar A, Mani G.
europepmc +1 more source
Recent Advances in Direct Elimination of Carboxylic Acids to Olefins. [PDF]
Zhou Y, Wei Z, Zhang Y, Zhang Y, He K.
europepmc +1 more source

