Results 51 to 60 of about 1,722,857 (346)

An improved palladium-based DMFCs cathode catalyst

open access: yes, 2004
A novel carbon-supported palladium-rich Pd3Pt1/C catalyst prepared by a modified polyol process showed a better cell performance than Pt/C in direct methanol fuel cells, which may be attributed to palladium's inactivity to methanol electro-oxidation ...
Yang, SH   +6 more
core   +1 more source

Field Report from Collaborative Research Center 1625: Heterogeneous Research Data Management Using Ontology Representations

open access: yesAdvanced Engineering Materials, EarlyView.
A unified research data management framework for heterogeneous materials data is presented. The system integrates multimodal datasets using ontologies and knowledge graphs, enabling interoperability and FAIR (findable, accessible, interoperable, reusable) data principles. By linking data across scales and workflows, it supports reproducible, Artifitial
Doaa Mohamed   +6 more
wiley   +1 more source

Development of a Highly Efficient 3D RuPdBi/NG Electrocatalyst for Ethylene Glycol Oxidation in an Alkaline Media

open access: yesInternational Journal of Electrochemical Science, 2017
Palladium (Pd) based catalysts are being considered as one of the most attractive area of research among researchers in recent years. These catalysts are used in the alcohol oxidation in fuel cells, despite it results in not enough higher oxidation ...
Yaxi Pan   +7 more
doaj   +1 more source

Water‐Compatible SuFEx‐Active Diazonium Linchpin Platform for Rapid Modular Diversification and On‐DNA Functionalization

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur fluoride exchange (SuFEx) is a powerful click platform, yet water‐compatible multifunctional linchpins remain elusive. Here, we report decagram‐scalable diazonium linchpins that enable rapid Pd‐catalyzed diversification and direct, catalyst‐free on‐DNA ligation in aqueous media.
Seok Ju Hong   +5 more
wiley   +1 more source

Palladium-catalyzed cross-couplings in the synthesis of agrochemicals

open access: yesAdvanced Agrochem, 2022
Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross ...
Yuxin Zhu, Wenfeng Dong, Wenjun Tang
doaj   +1 more source

1,2-bis-(ditertbutylphosphinomethyl)benzene in catalysis [PDF]

open access: yes, 2012
Different diphosphine ligands having the structure shown below have been studied for carbonylation and hydroformylation reactions. Depending on the substituent on the phosphorus atoms the electronic and steric properties can be tuned to direct the ...
Jiménez, Cristina
core   +2 more sources

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Electronic Modifictions in Supported Palladium Catalysts

open access: yes, 1994
XPS and IR spectroscopy indicate that the electron density of the supported metal clusters in Pd/LTL catalysts is a function of the support acidity/alkalinity. In addition, the neopentane and propane hydrogenolysis TOF's increase with increasing support acidity from alkaline to acidic.
Koningsberger, D.C.   +6 more
openaire   +2 more sources

Palladium-on-Charcoal Catalysts

open access: yesPlatinum Metals Review, 1961
The performance of charcoal-based catalysts cannot be described simply in terms of their mesh size and noble metal content, as many factors can cause wide variations in activity, selectivity and resistance to poisoning. It is possible, however, by close collaboration between catalyst manufacturer and user, and by suitable choice of base and production ...
J. C. Chaston, E. J. Sercombe
openaire   +1 more source

Electrospun Wood‐Derived Biopolymers as Electrodes in Electrochemical Energy Storage Technologies

open access: yesAdvanced Functional Materials, EarlyView.
Electrospinning transforms wood‐derived cellulose and lignin into architecturally defined, binder‐free carbon electrodes with tuneable porosity and functionality. This review shows how fibre design enables decoupled charge and mass transport, enhancing performance across battery systems, while identifying key challenges in spinnability, scalability ...
Michael W. Thielke   +3 more
wiley   +1 more source

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