Results 171 to 180 of about 187,142 (275)

Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex

European Journal of Inorganic Chemistry, EarlyView.
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki, Frank W. Heinemann, Leonardo D. Slep, Alejandro Cadranel   +3 more
wiley   +1 more source

Thermal Management in Metal Hydride Hydrogen Storage Reactors: Mechanisms, Architectures, and Design Trade-Offs. [PDF]

Nanomaterials (Basel)
Hou Q, Xu X, Deng K, Li Y, Wang Q, Xu Z, Ji J, Zhou Y, Ding Z.   +8 more
europepmc   +1 more source

Mechanistic Paths for the Gold(I)‐Catalyzed Heteroannulation of Salicylic Amides With Apolar Alkynes Explored With Density Functional Theory Calculations

European Journal of Organic Chemistry, EarlyView.
A manifold of catalytic reaction paths can operate in the Au(I)‐catalyzed heteroannulation of salicylic amides and alkynes. However, a subtle initial nucleophilic advantage of N versus O and a kinetic bottleneck at an advanced stage of the mechanistic machinery seems to suffice for the reaction to run on a single path and with exquisite selectivity. We
Ioannis Stylianakis, Evaggelia Vlachou, Carlos Silva López, Antonios Kolocouris   +3 more
wiley   +1 more source

Induction of Autoimmune Myocarditis in Diversity Outbred Mice. [PDF]

Biology (Basel)
Sur M, Mone K, Singh S, Rasquinha MT, Riethoven JM, Mukhopadhyay I, Sobel RA, Reddy J.   +7 more
europepmc   +1 more source

Synthetic Implications of Spin States in the Reactivity of Ni Intermediate Complexes in Coupling Reactions

European Journal of Organic Chemistry, EarlyView.
The formation of triplet Ni(II) complexes by activation of bromoalkenes with alkyl‐ or boryl Ni(I) is key to control the outcome of the reductive cross‐coupling of bromoalkanes precluding the formation of alkylboronates. We present a mechanistic study on the Ni‐catalyzed cross‐coupling reaction of bromoalkanes with diboron compounds as reductants.
Diego J. Cárdenas
wiley   +1 more source

Improvement of Peak Integration in Capillary Electrophoresis: Reference Data Set No. 1

ELECTROPHORESIS, EarlyView.
ABSTRACT Capillary electrophoresis (CE) often provides superior separation of macromolecules such as monoclonal antibodies (mAbs), a major biopharmaceutical class, compared with liquid chromatography. However, electropherograms frequently exhibit complex baselines and peak shapes that are not reliably handled by integration algorithms designed for ...
Marlon Krompholz, Timothy Blanc, Huixin Lu, Patricia Christensen, Frédéric Ginot, Gábor Járvás, Trang D. Nguyen, Ashley Prout, Timothy Riehlman, Brian Wei, Andrei Hutanu, Steffen Kiessig, Knut Baumann, Cari E. Sänger‐van de Griend, Hermann Wätzig   +14 more
wiley   +1 more source

An exhaustive cell-based screen coupled with an intracellular-induced lux-based reporter identified bioactive molecules that inhibit host cell infection by intracellular pathogens. [PDF]

Front Cell Infect Microbiol
Adani B, Plotnikov A, Lueken L, Shomer I, Shurrush K, Meyer N, Künnemann K, Kellermann M, Margulies D, Grassl GA, Hensel M, Barr HM, Gal-Mor O.   +12 more
europepmc   +1 more source

Techno‐Economic and Life Cycle Assessment of a Nanofluid‐Based Concentrated PV/T–TEG Hybrid System With Spectral Filtering

Energy Science &Engineering, EarlyView.
A novel cascade nanofluid‐based PV/T–TEG hybrid system (CS4) achieves 81.1% thermal and 18.75% exergy efficiency while cutting CO₂ emissions by 7.8 tons year⁻¹. The system delivers superior energy performance, economic savings, and environmental benefits, offering a sustainable pathway for next‐generation solar energy applications.
Abdelhak Lekbir, Samir Hassani, Saad Mekhilef, Kok Soon Tey, Abdullahi Mohamed Samatar   +4 more
wiley   +1 more source

Immune imbalance and autoimmune mechanisms in plasma cell mastitis: current perspectives. [PDF]

Front Cell Dev Biol
Xue B, Jiang Y, Lei Y, Liu X, Li J, Li Y, Zhang B, Wang Y, Jia H.   +8 more
europepmc   +1 more source

Numerical Simulation and Analysis of Heat Transfer Characteristics in Gradient‐Porosity Foam Copper Composite Phase Change Materials

Energy Science &Engineering, EarlyView.
This study investigates the heat transfer characteristics of copper‐foam composite phase change materials with different gradient porosities. Three models with uniform porosity and three models with gradient porosities are developed to examine their effects on temperature distribution and melting behavior. ABSTRACT Phase change materials (PCMs) exhibit
Wei Yang, Chenchen Bao, Guofeng Zhou, Yuxi Qiao, Ruiling Yu, Manfeng Li, Linlin Zhang   +6 more
wiley   +1 more source