Self‐Immolative Gels: Programmable Degradation Using Self‐Immolative Linkers and Polymers
Self‐immolative linkers and polymers undergo bond‐cleaving reaction cascades in response to specific stimuli. Their incorporation into gels can be harnessed to release cargo, induce property changes, or trigger degradation in a highly controlled manner. These functions can be employed in applications such as sensing and drug delivery.
Chuanfeng Li, Elizabeth R. Gillies
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Green Electrochromic Film Formation via Phenylcarbazole Polymerization in Ionic Liquids
The scheme depicts the three‐step electropolymerization of two electrochromic polycarbazole derivatives, 4‐(9H‐carbazol‐9‐yl)phenol and 4‐(3‐methoxy‐9H‐carbazol‐9‐yl)phenol, performed at constant potential using the green ionic liquid BMIM TFSI. This medium enables controlled polymer growth and enhances electrochromic performance, yielding robust and ...
Carolina Gascó +3 more
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Biomechanical evidence for occupational specialization in Mesolithic-Neolithic hunter-gatherers from Zvejnieki, Latvia. [PDF]
Temple DH +3 more
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The development of chemoselective catalysts that operate across structurally diverse substrates remains a long‐standing challenge. Here, we demonstrate that a random heteropolymer bearing carboxylic acid and urea residues functions as a general epoxidation catalyst for olefinic quaternary ammonium salts.
Yusei Fujii +2 more
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Modeling identities among the first-sedentary communities: Emergence of clay personal ornaments in Epipaleolithic Southwest Asia. [PDF]
Davin L +9 more
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Cyclen tetra‐amide derivatives provide a privileged ligand platform for controlling second‐coordination sphere structure. Hydrogen‐bond networks in the second‐coordination sphere are leveraged to stabilize a EuII‐containing cyclen tetra‐amide derivative in physiologically relevant conditions by limiting the access of O2, establishing a design‐principle
Andrea L. Batchev +5 more
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Achiral benzoic acid appended helical polymers for the copper-catalyzed asymmetric Diels-Alder reaction and Michael addition with excellent enantioselectivity and recyclability. [PDF]
Ti QH, Mo MY, Gao RT, Liu N, Wu ZQ.
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The synergic action of ascorbic acid and NHC^N ligands enables Au(I) oxidation with electron‐rich aryldiazonium salts. ABSTRACT The synergistic action of ascorbic acid and NHC^N ligands enables the challenging oxidation of Au(I) with electron‐rich aryldiazonium salts in the absence of a cocatalyst and/or irradiation. EPR, NMR, and x‐ray analyses reveal
Paula G. Cárdenas‐Cárdenas +7 more
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Self-sorting systems of photoresponsive polymer micelles: isomerization drives reversible and switchable self-assembly. [PDF]
Kanno R, Ouchi M, Terashima T.
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Mechanism of wettability alteration, interfacial tension reduction, and oil recovery by novel nanocomposite. Abstract The development of stable nanofluids (NFs) for enhanced oil recovery (EOR) relies on optimizing interactions between reservoir rocks and fluids.
Ehsan Jafarbeigi +2 more
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