Regiospecific photohydroxyalkylation of pentafluoropyridine
Journal of Heterocyclic Chemistry, 1978AbstractIrradiation of 1‐hydroxyalkane solutions of pentafluoropyridine in the presence of benzo‐phenone resulted in regiospecific substitution at position 4, thus forming 2,3,5,6‐tetrafluoro‐4‐(1‐hydroxyalkyl)pyridine.
Boris Sket, Marko Zupan
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Chemistry and Dynamics of Interaction of Nucleosides with Pentafluoropyridines.
ChemInform, 2005AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.
V V, Litvak +2 more
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ChemInform Abstract: REGIOSPECIFIC PHOTOHYDROXYALKYLATION OF PENTAFLUOROPYRIDINE
Chemischer Informationsdienst, 1978AbstractBei der Photolyse erhält man aus Benzophenon (II) und den Carbinolen (I) über radikalische Zwischenstufen (III) und (IV) neben den Dimeren (V) in Gegenwart von Pentafluorpyridin (VI) die Substitutionsprodukte (VII).
B. SKET, M. ZUPAN
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Reaction of sodium diethylnitroxide with fluorobenzenes, pentafluoropyridine and halogenopyridines
Journal of Fluorine Chemistry, 1989Abstract Treatment of pentafluoropyridine with sodium diethylnitroxide in diethyl ether gave tetrafluoropyridines 4-RC 5 F 4 N(R = ONEt 2 , NEt 2 , NHEt and O − H 2 N + Et 2 ); in the presence of p -dinitrobenzene only the hydroxylamine (R = ONEt 2 ) was detected.
Ronald Eric Banks +2 more
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ChemInform Abstract: REACTION OF PENTAFLUOROPYRIDINE WITH BIFUNCTIONAL NUCLEOPHILES
Chemischer Informationsdienst, 1975AbstractUnter verschiedenen Bedingungen setzt sich Pentafluorpyridin (I) mit den bifunktionellen Nucleophilen (II) zu den 4‐substituierten Derivaten (III) um.
JERZY WIELGAT, ZDZISLAW DOMAGALA
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ChemInform Abstract: THE PENTAFLUOROPYRIDINE CATION C5F5N(1+)
Chemischer Informationsdienst, 1981AbstractOäAsFg oxidiert Pentafluorpyridin (I) zu dem Kation (II), das sich thermisch unter Disproportionieren zu einem Gemisch des Addukts (III) mit dem (I)′ASF5‐Addukt zersetzt.
K. + ZUECHNER +3 more
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BINOL Modification via SNAr Reactions with Pentafluoropyridine
Mendeleev Communications, 2015(R)- and (S)-binaphthyl-2,2’-diols (BINOLs) smoothly react with pentafluoropyridine without racemization to give (R)- and (S)-2,2’- bis(tetrafluoropyridin-4-yloxy)-1,1’-binaphthyls. The 2(6)-positioned pyridine fluorine atoms can be replaced with amino moieties by reactions with amines.
Konstantin Yu. Koltunov +1 more
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Nuclear magnetic double and triple resonance studies on pentafluoropyridine
Journal of the Chemical Society, Faraday Transactions 2, 1972Removing the broadening effect of the 14N nucleus by strong irradiation has made it possible to determine all the relative signs of the FF coupling constants in pentafluoropyridine by double and triple resonance experiments. It is also shown that the coupling constants depend upon solvent.
V. Barboiu, J. W. Emsley, J. C. Lindon
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Hetarenium salts from pentafluoropyridine. Syntheses, spectroscopic properties, and applications
Journal of Heterocyclic Chemistry, 2007Abstractmagnified imageReaction of pentafluoropyridine with nucleophilic heteroaromatics such as 4‐(dimethylamino)pyridine, 4‐(pyrrolidin‐1‐yl)pyridine, 4‐(morpholin‐4‐yl)pyridine, 4‐aminopyridine, and 3,4‐diaminopyridine resulted in the formation of 4‐hetarenium substituted tetrafluoropyridines.
Andreas Schmidt +3 more
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Highly Functionalized Heterocycles and Macrocycles from Pentafluoropyridine
ChemInform, 2005AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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