Catalytic Oxidative Ligand Transfer of Rh-Carbynoids and Alkyl Iodides. [PDF]
Esteve Guasch J, Pal D, Suero MG.
europepmc +1 more source
Contribution of biomass and biofuel emissions to trace gas distributions in Asia during the TRACE-P experiment [PDF]
Blake, DR +15 more
core
Abstract The regio‐ and stereoselective hydroxylation of unactivated C(sp3)‐H bonds is an important reaction in organic synthesis. While bacterial alkane monooxygenase AlkB catalyzes the terminal hydroxylation of aliphatic esters with excellent regioselectivity, the molecular principles of substrate recognition and selectivity of this integral membrane
Jelena Spasic +8 more
wiley +1 more source
Regiodivergent Lewis acid catalysis of bicyclo[1.1.0]butanes with 2-naphthols. [PDF]
Fan L +6 more
europepmc +1 more source
α,γ, δ‐Tribrom‐pentan aus α, ε‐Dibrom‐pentan [PDF]
Julius v. Braun, Georg Kirschbaum
openaire +1 more source
Ferrocene‐based N‐heterocyclic tetrylenes [Fe{(η5‐C5H4)NBTrip2}2E](E = GePb; Trip = C6H2‐2,4,6‐iPr3)exhibit long EN and short BN bonds, in agreement with increased electrophilicity due to the ‐M effect of the N‐substituents, whose stericdemand prevents coordination of 4‐(dimethylamino)pyridine (DMAP) to theplumbylene PbII atom, but allows the ...
Sneha Mullassery +3 more
wiley +1 more source
Synthesis of Bicyclo[1.1.1]Pentane Z-Substituted Enamides, Enol Ethers, and Vinyl Sulfides Using Iodine (III) Reagents. [PDF]
Lee N, Dechent J, Grinhagena E, Waser J.
europepmc +1 more source
The Diarylprolinol Silyl Ethers: After 20 Years Still Opening New Doors in Asymmetric Catalysis
Catalysis Rules! The year 2025 marks the 20th anniversary of diarylprolinol silyl ethers in asymmetric organocatalysis. During the first decade after their discovery, these catalysts have been established as one of the most versatile tools in aminocatalysis. Although now considered mature, recent years have witnessed renewed innovation.
Enrico Marcantonio +2 more
wiley +2 more sources
Nucleophilic Substitution of 1,3-Diiodobicyclo[1.1.1]pentane: Synthesis of Bicyclo[1.1.1]pentylpyridinium, Quinolinium, Isoquinolinium, and Pyrazolium Salts. [PDF]
Monroe HJC +6 more
europepmc +1 more source
Designed Water Capture in Terpene Synthase Catalysis
Engineering of water capture in terpene synthases remains very challenging. We identified two regions in the selinadiene synthase active site pocket that can influence deprotonation or water capture in the final catalytic step and demonstrate a designed‐in switch in product outcome.
Prabhakar L. Srivastava +2 more
wiley +1 more source

