Proton conductive perovskite solid solutions with enhanced mechanical stability
Solid State Ionics, 1996Abstract Perovskite solid solutions with formula SrYb0.05(Ce1 − xZrx)0.95O3 − α (x = 0, 0.25, 0.5, 0.75 and 1) were prepared. Their electrical behaviour was investigated using impedance spectroscopy between 200 and 1000 °C in different atmospheres, with and without hydrogen. Conductivities and their activation energies were obtained.
Thomas Matzke, Marcella Cappadonia
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Planar Defects and Incommensurate Phases in Highly Ordered Perovskite Solid Solutions
Physical Review Letters, 2002A first-principles-derived approach is used to study the effects of planar defects on structural properties of a rocksalt-ordered Pb(Sc0.5Nb0.5)O3 alloy. These defects lead to unusual features, including a less symmetrical ground state with respect to the perfectly ordered material.
Igor A, Kornev, L, Bellaiche
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LaAl1–xMnxO3 perovskite-type oxide solid solutions: structural, magnetic and electronic properties
Physical Chemistry Chemical Physics, 2003d-Al2O3 supported La, Mn, Co and Fe contg. catalysts were prepd. by impregnation of d-Al2O3 with citrate-type precursors and calcination at 1073 K. The catalysts were characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), X-ray absorption spectroscopy (XAS), and BET sp. surface area detn. XRD revealed the presence of d-
CORDISCHI D. +4 more
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AbstractOxidmischkristalle vom Perowskit‐Typ wie z.B. La, ‐xCaxYO3 ‐a oder Srlrog ° In0‐1O3 ‐o, besitzen, wie qualitativ mit einer elektrochemischen Methode bestätigt wird, in H, ‐Atrnosphäre bei hohen Temp. Protonenleitfähigkeit.
T. TAKAHASHI, H. IWAHARA
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Microheterogeneous Solid Solutions in Perovskites: Formation, Microstructure, and Catalytic Activity
ChemInform, 2004AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
L. A. Isupova +5 more
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Phase Transitions in Perovskite Solid Solutions with Incipient Ferroelectrics
Ferroelectrics, 2004The impurity-induced ferroelectric phase transitions in incipient perovskite ferroelectrics are discussed along with improper ferroelastic phase transitions. It is shown that the critical concentration of impurities is proportional to 1/ϵ3/2 and that the ferroelectric phase transitions probably suppress ferroelastic transitions.
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Perovskite solid solutions La0.75Bi0.25Fe1−xCrxO3: Preparation, structural, and magnetic properties
Journal of Solid State Chemistry, 2017Abstract Solid solutions of La0.75Bi0.25Fe1−xCrxO3 (x = 0.1, 0.25, 0.5, and 0.75) prepared by conventional solid state reaction have been studied by means of X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic measurements. The NPD and XRPD patterns indicate orthorhombic structure (space group Pnma) for all compositions in ...
S.A. Ivanov +6 more
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Probabilistic models of a local structure of perovskite solid solutions
Bulletin of the Russian Academy of Sciences: Physics, 2007The magnitudes of the structure amplitudes (|F(h, k, l)|) of the X-ray diffraction reflections measured for a PbIn1/2Nb1/2O3 single crystal are compared with those calculated with the use of a sequence of probability-theoretical models constructed for the structure of the PbIn1/2Nb1/2O3 compound.
K. Yu. Gufan +2 more
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Catalytic oxidation of CO on LaMn1−xFexO3 perovskites solid solution
Journal of Molecular Catalysis A: Chemical, 2014Abstract Catalytic CO oxidation was studied over LaMn1−xFexO3 perovskites prepared by co-precipitation and rotor-vapor citrate method. The catalysts were characterized by X-ray diffraction (XRD), Transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS).
Saijing Zheng +3 more
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Lithium ion conductivity of A-site deficient perovskite solid solutions
Journal of Power Sources, 1999Abstract Over twenty of A-site deficient perovskite solid solution with Li + ion conductivity (Li-ADPESSs) were prepared with the M and Li concentration fixed at M 0.56 Li 0.33 TiO 3 in the five series: (A) (La 1− X Nd X ) 0.56 Li 0.33 TiO 3 , (B) La 0.56 Li 0.33 M(IV) X Ti 1− X O 3 [M(IV)=Zr,Hf], (C) (Ca 1− X Sr X ) 0.56 Li 0.33 Ta 0.56 ...
Yasuhiro Harada +3 more
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