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Peroxynitric Acid Decay Mechanisms and Kinetics at Low pH
The Journal of Physical Chemistry A, 1997An efficient spectroiodometric method is described for the quantification of peroxynitric acid, HOONO2, and H2O2 in dilute solutions. HOONO2 reacts with I- in acidic media with a rate constant of 1200 ± 300 M-1 s-1. At 22 °C and pH 1.7, in the presence of 1.00 mM Na2EDTA, the average lifetime for HOONO2 thermal decay was found to be 49 ± 26 min, longer
Jean-Michel Régimbal +1 more
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