Photothermal Perylene Bisimide Hydrogels. [PDF]
AbstractGels formed using a perylene bisimide (PBI) as a low molecular weight gelator can show the photothermal effect. Formation of the PBI radical anion results in new absorption bands forming, meaning that subsequent irradiation with a wavelength of light overlapping with the new absorption band leads to heating of the gel. This approach can be used
Thomson L +4 more
europepmc +4 more sources
Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels [PDF]
We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene bisimide (PBI) units.
Ana M. Castilla +7 more
doaj +8 more sources
Using Solution History to Control Hydrogel Properties of a Perylene Bisimide. [PDF]
pH dependence on water soluble aggregates is well‐known in the field of low molecular weight gelators (LMWGs), with different aggregates sometimes having very different properties depending on their final pH.
Ginesi RE +4 more
europepmc +2 more sources
Mechanoresponsive Self-Assembled Perylene Bisimide Films. [PDF]
AbstractIn this work, self‐assembled amino‐acid appended perylene bisimides (PBIs) have been studied that when processed into thin films change their resistivity in response to being bent. The PBIs assemble into structures in water and form thin films upon drying.
Adams V +3 more
europepmc +6 more sources
Deracemization of Carbohelicenes by a Chiral Perylene Bisimide Cyclophane Template Catalyst. [PDF]
Deracemization describes the conversion of a racemic mixture of a chiral molecule into an enantioenriched mixture or an enantiopure compound without structural modifications. Herein, we report an inherently chiral perylene bisimide (PBI) cyclophane whose
Weh M +4 more
europepmc +2 more sources
Chiral Perylene Bisimide Dyes by Interlocked Arene Substituents in the Bay Area. [PDF]
A series of perylene bisimide (PBI) dyes bearing various aryl substituents in 1,6,7,12 bay positions has been synthesized by Suzuki cross‐coupling reaction.
Renner R +4 more
europepmc +2 more sources
Photoinduced stepwise charge hopping in π-stacked perylene bisimide donor-bridge-acceptor arrays. [PDF]
The mechanistic understanding of light-driven charge separation and charge-carrier transport within the frameworks of π-conjugated molecules is imperative to mimic natural photosynthesis and derive synthetic materials for solar energy conversion. In this
Ernst L, Song H, Kim D, Würthner F.
europepmc +2 more sources
Real-time Observation of Structural Dynamics Triggering Excimer Formation in a Perylene Bisimide Folda-dimer by Ultrafast Time-Domain Raman Spectroscopy. [PDF]
In π‐conjugated organic photovoltaic materials, an excimer state has been generally regarded as a trap state which hinders efficient excitation energy transport.
Hong Y +6 more
europepmc +2 more sources
Globular Aggregates Stemming from the Self-Assembly of an Amphiphilic N-Annulated Perylene Bisimide in Aqueous Media [PDF]
Herein, we describe the synthesis of highly emissive amphiphilic N-annulated PBI 1 decorated with oligo ethylene glycol (OEG) side chains. These polar side chains allow the straightforward solubility of 1 in solvents of different polarity such as water ...
Manuel A. Martínez +4 more
doaj +2 more sources
Supramolecular Chiral Discrimination of D-Phenylalanine Amino Acid Based on a Perylene Bisimide Derivative [PDF]
The interaction between homochiral substituted perylene bisimide (PBI) molecule and the D enantiomer of phenylalanine amino acid was monitored. Spectroscopic transitions of PBI derivative in aqueous solution in the visible range were used to evaluate the
Simona Bettini +12 more
doaj +2 more sources

