Results 271 to 280 of about 2,751,852 (326)

Ruthenium‐Catalyzed Azide‐Selenoalkyne Cycloadditions: A Combined Synthetic–Computational Study into Reaction Scope, Mechanism, and Origins of Regioselectivity

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A ruthenium‐catalyzed azide–alkyne cycloaddition (RuAAC) reaction is reported for the synthesis of selenium‐substituted triazole products. Reaction regioselectivity is dependent on the identity of the non‐selenium substituent of the alkyne, which challenges the perceived understanding of RuAAC regioselectivity.
Frances E. Bugden   +9 more
wiley   +1 more source

Chiral Potassium Brønsted Base‐Catalyzed Stereoselective Synthesis of 1,3‐Diols via a Tandem Allylic Isomerization/Asymmetric Aldol–Tishchenko Reaction

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Chiral potassium base catalysts featuring 1,1´‐bi‐2‐naphthol‐derived chiral crown ethers as ligands promote a tandem allylic isomerization/asymmetric aldol‐Tishchenko reaction of allylic alcohols and aldehydes. This method provides enantioenriched 1,3‐diols with excellent diastereoselectivity and high enantioselectivity, thereby expanding the synthetic
Hiroki Ishikawa, Masahiro Sai
wiley   +1 more source

Correction: Formation permeability estimation using mud loss data by deep learning. [PDF]

open access: yesSci Rep
Abdollahfard Y   +4 more
europepmc   +1 more source

Proton‐Coupled Electron Transfer Processes in the Decarboxylative Synthesis of C‐4 Substituted Chroman‐2‐Ones

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
This research presents a new mild photocatalytic method enables C‐4 alkylation of chroman‐2‐one derivatives with primary alkyl radicals. This radicals are generated via oxidative PCET process. Developed approach offers broad substrate scope, scalability under photo‐flow conditions, and mechanistic evidence supports a decarboxylation pathway under polar
Ewelina Kowalska   +4 more
wiley   +1 more source

CEMPRI, a primary cementing software for vertical onshore wells as a tool for petroleum engineering education

open access: diamond
Marcos Andrés Jiménez Moreno   +3 more
openalex   +1 more source

Electrochemical Trifluoromethylchlorosulfonylation of Alkenes via Copper‐Mediated SO2Cl Radical Transfer

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
This article reports an electrosynthetic method for vicinal trifluoromethylchlorosulfonylation of alkenes using [Cu(MeCN)4]PF6 and triethylamine, without elaborate ligands. The reaction efficiently adds CF3 and SO2Cl across diverse unactivated alkenes with broad functional group tolerance.
Sachini Rodrigo   +2 more
wiley   +1 more source

Performance and emission characteristics of waste cooking oil biodiesel blends in sustainable fuel applications. [PDF]

open access: yesSci Rep
Azarudeen JM   +9 more
europepmc   +1 more source

One‐Step Copper‐Assisted Synthesis of α‐(Styrylsulfonyl)amides via SO2 Incorporation Under Visible Light

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
α‐(Styrylsulfonyl)amides are prepared from α‐bromoamides, SO2, and styrenes in a one‐step photoredox‐catalyzed reaction in the presence of a copper complex. Additionally, related ester analogs could be synthesized following the same procedure. The mechanism of the newly developed method is investigated and model postmodification reactions are carried ...
Nejc Petek, Till Opatz
wiley   +1 more source

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