Results 181 to 190 of about 12,918 (277)

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

Chemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano, Paolo Della Sala, Placido Neri, Donato De Simone, Rocco Del Regno, Margherita De Rosa, Carmine Gaeta, Carmen Talotta   +7 more
wiley   +1 more source

Living Cationic Polymerization of Silyl-Protected β-Methyl Vinyl Ethers (Propenyl Ethers): Synthesis of Hydroxy-Functional Polymers with High <i>T</i>_g and LCST-Type Thermoresponse. [PDF]

Molecules
Watanabe K, Yamada R, Namikoshi T.
europepmc   +1 more source

Metal‐Ion Regulated Light‐Free Z→E Isomerization of Azobenzene Glycomacrocycle

Chemistry – A European Journal, EarlyView.
Metal ion‐catalyzed Z→E isomerization of photoswitchable azobenzene glycomacrocycle: A new azobenzene‐based glycomacrocycle is capable of forming a 1:1 complex with divalent metal ions in both E‐ and Z‐isomers. The complexes undergo light‐free Z→E isomerization in a timescale spanning from seconds to weeks.
Yang Zhou, Jinbiao Jiao, Mathieu Lordez, Jean‐Yves Salpin, Juan Xie   +4 more
wiley   +1 more source

High-valent sulfur fluorides as reactivity switches for PFAS-free benzene-azepine skeletal editing. [PDF]

Chem Sci
Nagababu C, Muramatsu T, Bacho MZ, Wu S, Ochiai S, Escorihuela J, Shibata N.   +6 more
europepmc   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo, Vincenzo Patamia, Chiara Zagni, Antonio Rescifina, Giuseppe Floresta   +4 more
wiley   +1 more source

Computational study of the effect of Lewis base additives and molecular spin state in SmI₂-chemistry. [PDF]

Chem Sci
Yu S, Romano C, Procter DJ, Kaltsoyannis N.   +3 more
europepmc   +1 more source

Detection of Testosterone Esters in Urine: Evidence of Trace‐Level Detectability in Doping Control Samples

Drug Testing and Analysis, EarlyView.
An ultrasensitive LC‐MS/MS method for detecting testosterone esters (T‐esters) in urine at sub–pg/mL levels is presented. This approach, employing Girard P derivatization, provides the first evidence of T‐esters' trace‐level detectability in human urine.
Daniel Pecher, Guro Forsdahl, Biljana Stojanovic, Günter Gmeiner   +3 more
wiley   +1 more source

Design principles for enantiospecific <i>para</i>- and <i>ortho</i>-[3,3] rearrangements of chiral aryl-allyl ethers.

Org Chem Front
Breinsperger J, Kaiser M, Gärtner P.
europepmc   +1 more source

Recent progress on Ni-catalysed alkyl-alkyl cross-coupling enabled by asymmetric hydrofunctionalization of alkenes. [PDF]

Chem Sci
He J, Kumar PB, Li Y, Yu Q, Shu W.
europepmc   +1 more source

Dual‐Stabilized Single‐Site Fe(II) for Catalytic Conversion of CO2 to Propiolic Acid Under Ambient Condition

EcoEnergy, EarlyView.
We develop a highly cost‐effective heterogeneous catalyst for efficient CO2 conversion to propiolic acid under mild conditions via a nano‐confined approach with porous MIL support. ABSTRACT Efficient conversion of carbon dioxide to organics has been a promising outlet for value‐added carbon dioxide consumption.
Bin Lei, Zhenzhen Zhou, Xiao Liu, Bo Li, Wenyuan Wang, Jian‐Gong Ma, Peng Cheng   +6 more
wiley   +1 more source