Results 201 to 210 of about 12,918 (277)

Ligand‐Level Chemical Activation: Coordination with Benefits

European Journal of Inorganic Chemistry, EarlyView.
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier, Agnideep Das, Marine Desage‐El Murr   +2 more
wiley   +1 more source

Three-Way Chemodivergent Derivatization of Non-Activated 2-Arylphenyl Benzyl Ethers. [PDF]

J Org Chem
Solas M, Sedano C, Suárez-Pantiga S, Kiriakidi S, Silva-López C, Sanz R.   +5 more
europepmc   +1 more source

Hydrosilane Chemistry: From Historic First Steps to Modern Applications

European Journal of Inorganic Chemistry, EarlyView.
This review covers the history of hydrosilanes, from their initial discovery to their modern applications. It highlights the pioneering work of chemists like Alfred Stock and Franz Fehér and discusses the modern ways of synthesis and use of hydrosilanes in printed electronics.
Uwe Böhme, Maik Gerwig
wiley   +1 more source

Nickel-Catalyzed Aminocarbonylation of Aryl Trifluoromethoxides. [PDF]

Org Lett
Liu ZW, Kuai CS, Wu XF.
europepmc   +1 more source

Dilithium Enediamide Derived From a 1,4‐Diaza‐1,3‐diene: Reactivity of a Strongly N‐Basic, Highly C‐Nucleophilic Compound Toward C–H Acids

European Journal of Inorganic Chemistry, EarlyView.
The lithium enediamide complex 2 with intrinsically inverted C–N bond polarity combines strong basicity with unusual reactivity: deprotonation of malonates enables C–C bond formation without electron transfer. Depending on malonate substitution, electrophilic substitution or addition occurs at the enediamide CC bond.
Muhan Liang, Michael Kunze, Helmar Görls, Joachim Scholz   +3 more
wiley   +1 more source

Oxyalkylation of Alkenes via Triple Radical Sorting. [PDF]

J Am Chem Soc
Harstad LJ, MacMillan DWC.
europepmc   +1 more source

Dilithium Enediamide Derived From 1,4‐Diaza‐1,3‐Diene: An Electron Reservoir Enabling Variable Reactivity Toward Carbonyl Compounds

European Journal of Inorganic Chemistry, EarlyView.
Upon reduction of 1,4‐diaza‐1,3‐diene 1 to the dilithium enediamide 2, the polarity of the C = N bonds is reversed ‐ a classic case of umpolung. This behavior is particularly evident in reactions of the dianion 2 with carbonyl compounds and also explains why 1,4‐diaza‐1,3‐diene ligands do not always act merely as spectator ligands. 1,4‐Diaza‐1,3‐dienes
Muhan Liang, Michael Kunze, Helmar Görls, Joachim Scholz   +3 more
wiley   +1 more source

The Baeyer-Villiger Oxidation of Cubyl Ketones: A Synthetic Route to Functionalized Cubanols. [PDF]

Org Lett
Hind J, Fallis IA, Platts JA, Tredwell M.   +3 more
europepmc   +1 more source

A Hoveyda–Grubbs‐Type Olefin Metathesis Catalyst Bearing a Fluorinated Unsymmetrical NHC Ligand

European Journal of Inorganic Chemistry, EarlyView.
A fluorinated unsymmetrical NHC ruthenium complex was synthesised and employed as a catalyst for olefin metathesis reactions. The modification of the steric and electronic properties of the NHC ligand through the introduction of fluorine substituents results in improved activity but lower selectivity compared to the analogous non‐fluorinated NHC ...
Rubina Troiano, Concetta Liguori, Chiara Costabile, Fabia Grisi   +3 more
wiley   +1 more source

Diastereoselective Synthesis of <i>cis</i>-α,α'-Disubstituted Cyclic Ethers via Borane-Catalyzed Reductive Cyclization of Diketones. [PDF]

ACS Catal
Shcherbakov NV, Potin N, Mas-Roselló J.
europepmc   +1 more source