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The Claisen rearrangement of allyl phenyl ethers is a fundamental reaction in organic synthesis with a variety of applications in perfumes, flavors, pharmaceuticals, agrochemicals, polymers, fine chemicals, and intermediate industries. The development of
Ganapati D Yadav
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Reaction of Phenyl Isocyanate with 2,3-Epoxy Propyl Phenyl Ether (Phenyl Glycidyl Ether)
Nature, 1963REACTION of phenyl isocyanate and 2,3-epoxy propyl phenyl ether gives a one-to-one addition compound, and there is evidence to suggest this is 3 phenyl 5 phenoxy methyl 2 oxazolidono. The reaction is believed to be: This is similar to a reaction reported by A.
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1985
Oxidative metabolites of arachidonic acid produced by the 5-lipoxygenase pathway are potent mediators of hypersensitivity and inflammation (see O’Flaherty, 1982; Lewis and Austen, 1984 for reviews). Their proposed roles in the pathophysiology of asthma, chronic inflammation, and psoriasis have prompted an intense search for specific inhibitors of their
Stephen M. Coutts +12 more
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Oxidative metabolites of arachidonic acid produced by the 5-lipoxygenase pathway are potent mediators of hypersensitivity and inflammation (see O’Flaherty, 1982; Lewis and Austen, 1984 for reviews). Their proposed roles in the pathophysiology of asthma, chronic inflammation, and psoriasis have prompted an intense search for specific inhibitors of their
Stephen M. Coutts +12 more
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Rearrangement of bornyl phenyl ether
Russian Journal of Organic Chemistry, 2013We previously studied rearrangement of isobornyl phenyl ether under catalysis by acids and aluminum phenoxide [1]. Comparison of the experimental data obtained in the reaction catalyzed by acids and in the presence of aluminum phenoxide led us to presume that in the first case the rearrangement follows mainly intermolecular mechanism, and in the second,
I. Yu. Chukicheva +2 more
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Polymerization of allyl phenyl ether
Journal of Polymer Science: Polymer Chemistry Edition, 1976AbstractAllyl phenyl ether polymerized rapidly and quantitatively to a resin with a structure similar to a phenolic thermoset in the presence of boron trifluoride etherate at 50°C. The structure and properties of this polyphenol were studied. A reaction mechanism involving rearrangement was discussed.
K. M. Hui, L. C. Yip
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Mechanism of the Rearrangement of Phenyl Ethers
Nature, 1938WHEN certain phenyl ethers are heated at their boiling points, the non-aromatic group migrates from the oxygen to the nucleus. The more important groups which so migrate are allyl, benzyl and tert.alkyl. If the rearrangement of some of these ethers is effected in a suitable solvent, the migrating group is transferred, in part, to the solvent.
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Bis[4-(2-pyridylmethyleneamino)phenyl] ether
Acta Crystallographica Section C Crystal Structure Communications, 2001The title compound, C(24)H(18)N(4)O, is a bis-bidentate Schiff base ligand exhibiting pseudo-C(2) symmetry. The molecule is twisted about the central ether linkage and exhibits an imine E configuration. In the crystal, the molecules are linked by weak intermolecular C-H.N hydrogen bonds.
Tesouro Vallina A, Stoeckli-Evans H
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The Rearrangement of Phenyl Allyl Ethers. II. Phenyl Crotyl Ether
Journal of the American Chemical Society, 1936Walter M. Lauer, Herbert E. Ungnade
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Thermal Decomposition Of Phenyl Ether.
1950PhD ; Chemical engineering ; University of Michigan, Horace H. Rackham School of Graduate Studies ; http://deepblue.lib.umich.edu/bitstream/2027.42/182892/2/0001682 ...
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