A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini +9 more
wiley +1 more source
Oxygen-doped carbon-supported palladium nanoparticles boost the tandem hydrogenation-acetalization-hydrogenolysis of phenols and diphenyl ethers to cyclohexyl ethers. [PDF]
Jiang L +9 more
europepmc +1 more source
Chemoselective hydride abstractor iminometalloids, derived from O‐mesylacetoxime (MAO) using Rh2(II/II) or Cu(I) catalysts, can activate the C–Hα bonds of alcohols and aldehydes ultimately forming ketones, carboxylic acids, and esters even in the presence of C–H bonds with comparable bond strengths.
Raghunath Reddy Anugu +2 more
wiley +1 more source
Synthesis of Bicyclo[1.1.1]Pentane Z-Substituted Enamides, Enol Ethers, and Vinyl Sulfides Using Iodine (III) Reagents. [PDF]
Lee N, Dechent J, Grinhagena E, Waser J.
europepmc +1 more source
Amine-to-Halogen Exchange Enables an Amine-Acid Etherification. [PDF]
McGrath A +11 more
europepmc +1 more source
Photosensitized diradical rearrangement of alkenyl oxime ethers towards amino-featured oxiranes: reaction, mechanism, and structural prediction. [PDF]
Liu TM +6 more
europepmc +1 more source
Heterolysis vs Homolysis and <i>ortho</i>-<i>meta</i>-Effects in the Photohydrolysis of Biphenylamine Photocages. [PDF]
Lovrinčević V +8 more
europepmc +1 more source
Gold-Catalyzed Cyclizations of 4-Alkyl-2-yn-1-yl (Oxy)cyclohexa-2,5-dien-1-ones (1) to Develop Two Cyclizations via π-Alkyne versus π-Allene Activations. [PDF]
Kshirsagar AS, Liao PQ, Yang T, Liu RS.
europepmc +1 more source
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Photosensitized cyclodimerization of phenyl vinyl ether
Journal of the Chemical Society, Chemical Communications, 1972Irradiation of phenyl vinyl ether in the presence of aromatic compounds, such as dimethyl terephthalate, methyl benzoate, or benzonitrile, gives a mixture of trans- and cis-head-to-head cyclodimers of the olefin.
Satoshi Kuwata +2 more
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