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Sensitization to p-Phenylenediamine

Archives of Dermatology, 1965
p-Phenylenediamine (PPD) from 0.2 mg to 1.6 mg in water or in petrolatum was applied as a patch test to 501 patients with different dermatoses, asthma, hay fever, and venereal diseases. Of these patients 10.6% reacted within the first five days indicating previous hypersensitivity and 14.4% between the sixth and the 16th day indicating the initiation ...
openaire   +3 more sources

Occurrence, fate and chiral signatures of p-phenylenediamines and their quinones in wastewater treatment plants, China.

Water Research
p-Phenylenediamines (PPDs) and their derived quinones (PPD-Qs) are emerging pollutants. Information on their occurrence, fate and chiral signatures in the wastewater treatment plant (WWTP) and its receiving waters is scarce.
Jiabin Wang   +9 more
semanticscholar   +1 more source

Intercalated complexes of 1T′-MoS2 nanosheets with alkylated phenylenediamines as excellent catalysts for electrochemical hydrogen evolution

Journal of Materials Chemistry A, 2019
Two-dimensional 1T′ phase MoS2 that was intercalated with a series of alkylated p-phenylenediamines exhibits excellent catalytic activity toward hydrogen evolution reaction, supported by first-principles calculations.
I. Kwak   +9 more
semanticscholar   +1 more source

Occurrence and risk assessment of p-phenylenediamines and their quinones in aquatic environment: From city wastewater to deep sea.

Science of the Total Environment
p-Phenylenediamines (PPDs) and PPD-derived quinones (PPD-Qs) have been considered emerging pollutants recently. Their available data on sediment and sewage sludge are limited, especially the ecological risks.
Tingzhi Xu   +5 more
semanticscholar   +1 more source

P-phenylenediamines (PPDs) and 6PPD-quinone in tunnel PM2.5: From the perspective of characterization, emission factors, and health risks.

Journal of Hazardous Materials
P-phenylenediamines (PPDs) and a quinone derivative (6PPD-Q), as antioxidants added to tires, can inevitably enter into the environment during tire wear emission, posing potential health and ecological risks.
Nan Jiang   +9 more
semanticscholar   +1 more source

A niobium-catalyzed coupling reaction of α-keto acids with ortho-phenylenediamines: synthesis of 3-arylquinoxalin-2(1H)-ones

Green Chemistry, 2019
A general methodology to access valuable 3-arylquinoxalin-2(1H)-ones was developed, by the reaction of α-keto acids with ortho-phenylenediamines in the presence of ammonium niobium oxalate (ANO) as a catalyst.
Camila P. Ebersol   +6 more
semanticscholar   +1 more source

Sulfur-Promoted Access to 3-Arylquinoxalin-2-ones by Oxidative Coupling of o-Phenylenediamines with Arylacetates.

Organic Letters
We disclose the synthesis of 3-arylquinoxalin-2-ones from o-phenylenediamines and readily available arylacetates. The method harnesses the selective oxidative property of elemental sulfur in the presence of amine base catalyst and DMSO. The reactions are
L. A. Nguyen   +5 more
semanticscholar   +1 more source

Electrochemical Oxidative (4 + 2) Cyclization of Anilines and o-Phenylenediamines for the Synthesis of Phenazines.

Organic Letters
Phenazines, crucial constituents of nitrogen-containing heterocycles, widely exist in functional compounds. Herein, we report an anodic oxidative (4 + 2) cyclization between anilines and o-phenylenediamines for the uniform construction of phenazines in a
Peng-Fei Huang   +4 more
semanticscholar   +1 more source

Ultrasound-Assisted Polymerization of Dyes with Phenylenediamines: Facile Method To Design Polymeric Photosensitizers with Enhanced Singlet Oxygen Generation Characteristics and Anticancer Activity

Industrial & Engineering Chemistry Research, 2019
The present work reports for the first time ultrasound-assisted polymerization of Alizarin Red (AR), Amido Black 10B (AB-10B), 1,4-Benzoquinone (BQ) with ortho and para-phenylenediamines.
Neetika Singh   +3 more
semanticscholar   +1 more source

Imidazolium chloride-catalyzed synthesis of benzimidazoles and 2-substituted benzimidazoles from o-phenylenediamines and DMF derivatives

Tetrahedron, 2018
A facile, general, and economical synthesis of diversely functionalized benzimidazoles and 2-substituted benzimidazoles has been realized via the imidazolium chloride-catalyzed cyclization of o-phenylenediamines with DMF derivatives.
Zongjie Gan   +8 more
semanticscholar   +1 more source

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