Comparative transcriptome analysis of oil palm flowers reveals an EAR-motif-containing R2R3-MYB that modulates phenylpropene biosynthesis [PDF]
Background Oil palm is the most productive oil crop and the efficiency of pollination has a direct impact on the yield of oil. Pollination by wind can occur but maximal pollination is mediated by the weevil E. kamerunicus.
Ran Li +9 more
doaj +2 more sources
This research delves into phenylpropanoid metabolism, focusing on phenylpropene biosynthesis in the methyleugenol chemotype of basil (Ocimum basilicum L.).
İlker TÜRKAY +2 more
doaj +2 more sources
Comparison of the Metabolites in Fingered Citron Fruit (<i>Citrus medica</i> L. var. <i>sarcodactylis</i> Swingle) and Chayote (<i>Sechium edule</i>) Based on UPLC-Q-Orbitrap MS/MS. [PDF]
Untargeted UPLC‐Q‐Orbitrap MS/MS metabolomics was used to profile fingered citron (Citrus medica) from four Chinese production regions (CF1–CF4) and chayote (Sechium edule, CFM). Of 380 putatively annotated metabolites, 65 differential metabolites distinguished the five groups, clearly separating chayote from fingered citron and highlighting regional ...
Li B, Fan R.
europepmc +2 more sources
Novel Sulfonium Reagents for the Modular Synthesis of Spiro[2.3]Hexanes and Heteroatom-Containing Analogues: Synthesis, Application, and Evaluation as Bioisosteres. [PDF]
Strained spirocyclic spiro[2.3]hexane and its heteroatom‐containing derivatives, including previously underrepresented 5‐oxa‐1‐azaspiro[2.3]hexanes and 1,5‐diazaspiro[2.3]hexanes, were synthesized via a modular approach of insertion of cyclobutane‐, oxetane‐, and azetidine‐containing sulfonium reagents into alkenes, carbonyls and imines.
Natho P +10 more
europepmc +3 more sources
Sub-Micromolar Inhibition of SARS-CoV-2 3CLpro by Natural Compounds
Inhibiting the main protease 3CLpro is the most common strategy in the search for antiviral drugs to fight the infection from SARS-CoV-2. We report that the natural compound eugenol is able to hamper in vitro the enzymatic activity of 3CLpro, the SARS ...
Bruno Rizzuti +8 more
doaj +1 more source
Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation. [PDF]
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Krämer F, Downie TMH, Mulvey RE.
europepmc +3 more sources
An Investigation of the Storage and Biosynthesis of Phenylpropenes in Sweet Basil [PDF]
Abstract Plants that contain high concentrations of the defense compounds of the phenylpropene class (eugenol, chavicol, and their derivatives) have been recognized since antiquity as important spices for human consumption (e.g. cloves) and have high economic value.
Gang, David R +6 more
openaire +3 more sources
Ion-molecule pairs in leaving-group-promoted solvolytic elimination reactions
Solvolysis of 1-(1-methyl-1-phenylethyl)pyridinium cation (1-P+) in 25% vol acetonitrile in water at 60 degrees C provides the substitution product 2-hydroxy-2-phenylpropane (1-OH) and the elimination product 2-phenylpropene (3).
Thibblin, A,, Saeki, Y,
core +8 more sources
Antimicrobial Effect of Spices and Their Phytochemicals: A Novel Approach to Overcoming Antibiotic Resistance. [PDF]
This graphical abstract shows the antibacterial potential of phytochemicals from 15 spices, showcasing key compounds, their extraction methods, and mechanisms of action. It highlights membrane disruption, ROS generation, enzyme inhibition, and biofilm prevention as core antibacterial pathways.
De Silva HB +3 more
europepmc +2 more sources
Background. In order to make up for the defect that a single phase change material cannot meet the phase change temperature in a specific application field, three kinds of materials with higher phase change temperature are selected in this paper. Through
Hongzhi Zhu, Bin Guo, Zhi Li
doaj +1 more source

