Results 81 to 90 of about 41,966 (336)

The Zintl–Klemm Concept in the Amorphous State: A Case Study of Na–P Battery Anodes

Angewandte Chemie, EarlyView.
The long‐established Zintl–Klemm concept can be applied to amorphous materials just as well — as is shown here for disordered Na–P phases that are relevant for sodium‐ion battery anodes. Machine‐learning‐driven, quantum‐mechanically accurate simulations yiel insights into structure and bonding, and unlock the atomistic modeling of structural changes ...
Litong Wu, Volker L. Deringer
wiley   +2 more sources

Bridging Green Chemistry and Circular Economy: A Pathway to Sustainable Polyester Plastics Through Feedstock, Synthesis, and Waste Upcycling

Advanced Science, EarlyView.
This review summarizes green and low‐carbon strategies throughout the entire life cycle of polyester plastics, including sustainable monomer synthesis, optimization polymerization, efficient recycling, and advanced upcycling technologies. The synergistic implementation of these strategies is expected to significantly promote the development of a ...
Jinzhou Li, Junliang Chen, Yingbing Zhang, Li Wang, Pin Gao, Jianping Yang   +5 more
wiley   +1 more source

Solar‐driven co‐evolution of H2 and H2O2 from pure water splitting over emerging photocatalysts: Detailed mechanism and future outlook

PhotoMat, EarlyView., 2023
Photocatalytic water splitting for co‐evolution of H2 and H2O2 is deemed as a sustainable and promising strategy to address energy and environment issues, thus receiving increasing attention and realizing continuous achievements. This review aims to offer a deep understanding of the mechanism for H2 and H2O2 co‐evolution and the design principle of ...
Qiaohong Zhu, Jiaqi Wu, Mengmeng Du, Ning Zhang, Bocheng Qiu   +4 more
wiley   +1 more source

Switchable Reactivities of Metalated Phosphasilenes Regulated by Reversible 1,2‐Metal Migration

Angewandte Chemie, EarlyView.
We develop novel strategies for the facile synthesis of anionic phosphasilenes in the forms of both P‐metalation and Si‐metalation. The P‐metalated phosphasilene displays a pronounced π‐bond‐driven reactivity toward robust inert molecules, whereas the Si‐metalated analogue behaves as a silylene equivalent via a retro‐1,2‐silver migration.
Huaiyuan Zhu, Shicheng Dong, Xufang Liu, Xiyuan Li, Tobias Weng, Jun Zhu, Shigeyoshi Inoue   +6 more
wiley   +2 more sources

Non‐Equilibrium Synthesis Methods to Create Metastable and High‐Entropy Nanomaterials

Advanced Science, EarlyView.
ABSTRACT Stabilizing multiple elements within a single phase enables the creation of advanced materials with exceptional properties arising from their complex composition. However, under equilibrium conditions, the Hume–Rothery rules impose strict limitations on solid‐state miscibility, restricting combinations of elements with mismatched crystal ...
Shuo Liu, Chaochao Dun, Jeffrey J. Urban, Mark T. Swihart   +3 more
wiley   +1 more source

Toward Industrial Electrosynthesis of Ethylene: Energy‐Efficient and Stable Acetylene Semi‐Hydrogenation on a Copper Phosphide/MXene Electrocatalyst

Angewandte Chemie, EarlyView.
Cu3P nanoparticles anchored on MXene via Ti─O─P bonds exhibit enhanced stability and resist agglomeration during the electrochemical semi‐hydrogenation of C2H2 to C2H4. Ti3C2/Cu3P achieves a record energy efficiency of 23.0% at 0.2 A cm−2 and stable operation in a 4 cm2 MEA for over 100 h at 1.0 A.
Zeliang Wu, Qihui Guan, Tao Wang, Dongfang Li, Ming Lei, Wei Hong, Shixia Chen, Shijian Wang, Guoxiu Wang, Jun Wang   +9 more
wiley   +2 more sources

Electrochemical Nitrate Reduction Reaction to Ammonia at Industrial‐Level Current Densities

Advanced Science, EarlyView.
This review starts from the mechanism and theoretical basis of electrochemical nitrate reduction reaction (NO3−RR), and systematically summarizes and discusses the design strategies of industrial‐level current density catalysts. In addition, the progress of industrial‐level NO3−RR‐based electrolyzers, including flow reactor and membrane electrode ...
Zhijie Cui, Honghai Wang, Chunli Li, Wenchao Peng, Jiapeng Liu   +4 more
wiley   +1 more source

Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation

Angewandte Chemie, EarlyView.
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Felix Krämer, Thomas M. Horsley Downie, Robert E. Mulvey   +2 more
wiley   +2 more sources

A Rare but Potentially Fatal Poisoning; Aluminum Phosphide Poisoning

Journal of Pediatric Emergency and Intensive Care Medicine, 2017
Phosphide, a very toxic gas, is used in our country as aluminium phosphide tablets impregnated in clay. It is widely used since it has a very high diffusion capacity, whereby it can eradicate all living creatures in any form of their life cycle and does ...
Orkun Tolunay, Tamer Çelik, Gülperi Yücel, Ulaş Özdemir, Anıl Atmış, Asena Sucu, Ümit Çelik   +6 more
doaj   +1 more source

Aqueous Zinc‐Based Batteries: Active Materials, Device Design, and Future Perspectives

Advanced Energy Materials, EarlyView.
This review conducts a comprehensive analysis of aqueous zinc‐based batteries (AZBs) based on their intrinsic mechanisms, including redox reactions, ion intercalation reactions, alloying reactions, electrochemical double‐layer reactions, and mixed mechanisms, systematically discussing recent advancements in each type of AZBs.
Yan Ran, Fang Dong, Shuhui Sun, Yong Lei
wiley   +1 more source