A Bayesian meta‐learning framework is proposed for reaction outcome prediction in low‐data settings. It utilizes a literature‐mined dataset on asymmetric hydrogenation of olefins to build a pre‐trained model. This meta‐model is shown to return better predictions as compared to single‐tasks methods, such as random forest and graph neural networks, given
Sukriti Singh+1 more
wiley +2 more sources
SEPARATIONS BY SOLVENT EXTRACTION WITH TRI-n-OCTYL-PHOSPHINE OXIDE
J. C. White, W.J. Ross
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On the Interaction of Flavins with Phosphine-derivatives [PDF]
Franz Müller
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The catalytic conversion of CO2 into value‐added products provides an emerging strategy for reducing carbon emissions and improving environmental performance. This review compares different Life Cycle Assessment studies to evaluate the environmental impacts of CO2 conversion, focusing on the main challenges, technical limitations, and potential ...
Anastasia Pappa+3 more
wiley +1 more source
Human synenkephalin [1–53] (hSYN), an analogue peptide of shrew saliva neurotoxins, was synthesized and its structural characteristics studied. Synthetic hSYN potently activated the T‐type voltage‐gated Ca channel hCav3.2 but did not paralyze mealworms. These findings offer new insight into neurological disorder treatment and evolutionary mechanisms of
Ryo Fukuoka+5 more
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Asymmetric alkyl-alkyl coupling between electron-deficient and unactivated alkenes to access α-chiral phosphines by Ni catalysis. [PDF]
Zou JY+5 more
europepmc +1 more source
Zur Synthese phosphinkomplexierter d8-Metalltetrasulfide (Ni(II), Pd(II) und Pt(II)) mit Natriumpolysulfiden / On the Synthesis of Phosphine-Coordinated d8-Metal Tetrasulfides (Ni(II), Pd(II), and Pt(II)) with Sodium Polysulfides [PDF]
Max Schmidt, Gerhard Hoffmann
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Electrodeposited Iron‐Incorporated Cobalt Phosphide for Improved Supercapacitor Applications
The electrodeposition method has been used to synthesize Fe–CoP deposited on nickel foam, resulting in excellent cycling stability and capacitance retention compared to CoP and FeP. Furthermore, a detailed charge storage mechanism, emphasizing the enhanced electrochemical performance has been discussed. Supercapacitors have gained significant attention
Gaurav Pandey+2 more
wiley +1 more source
Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines
We present a one‐step deaminative Suzuki–Miyaura‐type coupling of anilines via fleeting diazonium intermediate with nitrate and bisulfite as the reagents. This represents the first application of the nitrate reduction strategy in transition metal catalysis of diazonium chemistry.
Chen‐Chen Li+6 more
wiley +2 more sources
Template-Directed Synthesis of Recognition-Encoded Melamine Oligomers Using a Base-Filling Strategy. [PDF]
Smith JT+4 more
europepmc +1 more source