Results 61 to 70 of about 186,275 (344)

Structural modification and performance regulation of atomically precise metal nanoclusters by phosphine

open access: yesPolyoxometalates, 2023
The ligand exchange-induced size/structural transformation (LEIST) reaction of metal nanoclusters gives researchers an effective way to understand the structural transition, broaden the methods of synthesis, and enhance the relevant performance of metal ...
Wenwen Fei   +4 more
doaj   +1 more source

Structural studies on the interactions of a P2N tridentate ligand with copper(I) silver(I) and S : a dissertation presented in partial fulfilment of the degree of Master of Philosophy at Massey University [PDF]

open access: yes, 1995
This thesis presents a study of the coordination chemistry, chemical reactivity, spectroscopy, structure and bonding of the hybrid polydentate ligand 2-(diphenylphosphino)-N-[2-(diphenylphosphino)benzylidene]benzeneamine (PNCP) with copper(I), silver(I ...
Fan, Xiaohong
core  

Sol–Gel Derived Polymer Precursors for Stereolithography of ZrC

open access: yesAdvanced Engineering Materials, EarlyView.
ZrC is a critical material target for extreme temperature conditions. This report describes a protocol for preparing ZrC ceramics via stereolithography and examines the impact of the polymer matrix on carbothermal reduction and mechanical stability of 3D printed ZrC.
Charles J. Rafalko   +2 more
wiley   +1 more source

Progress and Prospect of Control Technology for Stored Grain Pests ——Fumigation Insecticides

open access: yesLiang you shipin ke-ji, 2022
Phosphine and sulfuryl fluoride are two kinds of fumigation insecticides allowed for use in China and overseas. Phosphine is the “trump card” fumigation insecticide for stored grain, while Sulfuryl fluoride is mainly used as the phosphine resistance ...
XU Yong-an
doaj   +1 more source

Coordinatively unsaturated ruthenium complexes as efficient alkyne-azide cycloaddition catalysts [PDF]

open access: yes, 2012
The performance of 16-electron ruthenium complexes with the general formula Cp*Ru(L)X (in which L = phosphine or N-heterocyclic carbene ligand; X = Cl or OCH2CF3) was explored in azide−alkyne cycloaddition reactions that afford the 1,2,3- triazole ...
Broggi, Julie   +6 more
core   +2 more sources

DNA‐Templated 2D Heterostructures as Phototriggered Dynamic Nanohybrids: From Releasing Molecular Loads to Controlling Enzyme Biocatalytic Function

open access: yesAdvanced Functional Materials, EarlyView.
DNA strands are employed both as dynamic linkers and nanoscale templates for the integration of Ag2S nanoparticles on MoS2, which in turn imparted photothermal responsiveness; this feature permits the selective cargo (fluorophore, quantum dots or an enzyme) release from the MoS2 surface in response to local heat induced by light irradiation.
Kai Chen   +3 more
wiley   +1 more source

Controlling 3D Contractility via Engineered Fibrous Hydrogel Composites

open access: yesAdvanced Functional Materials, EarlyView.
A tunable composite contractile assembly (CCA) is developed that can permit or resist contraction without changing cell‐adhesion and density, unlike collagen whose inherent coupling of these ECM cues limits its use as a platform in contractility studies.
Karen L. Xu   +7 more
wiley   +1 more source

Activation of Tri(2-Furyl)Phosphine at a Dirhenium Centre: Formation of Phosphido-Bridged Dirhenium Complexes [PDF]

open access: yes, 2009
Reaction of tri(2-furyl)phosphine (PFu3) with [Re2(CO)10−n(NCMe)n] (n = 1, 2) at 40 °C gave the substituted complexes [Re2(CO)10−n(PFu3)n] (1 and 2), the phosphines occupying axial position in all cases.
Bennett, Dennis W.   +9 more
core   +2 more sources

Phosphine-Catalyzed Annulations of Azomethine Imines: Allene-Dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] Pathways [PDF]

open access: yes, 2011
In this paper we describe the phosphine-catalyzed [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] annulations of azomethine imines and allenoates. These processes mark the first use of azomethine imines in nucleophilic phosphine catalysis, producing ...
Benitez, Diego   +12 more
core   +2 more sources

Direct Observation of Early-stage Quantum Dot Growth Mechanisms with High-temperature Ab Initio Molecular Dynamics [PDF]

open access: yes, 2015
Colloidal quantum dots (QDs) exhibit highly desirable size- and shape-dependent properties for applications from electronic devices to imaging. Indium phosphide QDs have emerged as a primary candidate to replace the more toxic CdSe QDs, but production of
Jensen, Klavs F.   +3 more
core   +4 more sources

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