Results 61 to 70 of about 90,252 (235)

Phosphine-Catalyzed Intramolecular Vinylogous Aldol Reaction of Substituted Enones

open access: yes, 2021
We demonstrate the first phosphine-catalyzed intramolecular vinylogous aldol reaction (IVAR) of α-substituted enones. This strategy provides access to various pentannulated (hetero)­arenes and dibenzocycloheptanones incorporated with two contiguous ...
Atanu Mondal   +5 more
core   +1 more source

Metastable Polymers for Circular 3D Printing

open access: yesAdvanced Materials, EarlyView.
3D‐printed polymers are usually permanent and hard to recycle. Here, metastable polymers are designed to fall apart on demand. A chemical trigger unzips the printed material back into its original building blocks within minutes at room temperature.
Johannes Markhart   +2 more
wiley   +1 more source

Screening of phosphine resistance in Sitophilus oryzae (L.) (rice weevil) populations in Turkey

open access: yesJulius-Kühn-Archiv, 2018
In this study, the status and prevalence of phosphine resistance in Sitophilus oryzae (L.) (Coleoptera: Curculionidae) populations collected from Mersin and Konya Province in Turkey were investigated by conducting the discrimination concentration tests ...
Tingiş, Ahmet   +4 more
doaj   +1 more source

Fast Hydrogel Micro‐Actuators Driven by Electric Fields

open access: yesAdvanced Materials, EarlyView.
We report the fabrication of chemically programmable electroactuating microstructures through the first integration of two‐photon polymerization with electrically actuated gelatin methacrylate‐based hydrogels. By tailoring the charge of the polymer network, we demonstrate programmable polarity‐dependent bending, enabling microstructures that ...
Annaël Sort‐Montenegro   +6 more
wiley   +1 more source

Crystal Structure of Bis(2,4,6-trimethylphenyl)-phosphine Oxide

open access: yesMolbank, 2017
The single crystal structure of bis(2,4,6-trimethylphenyl)phosphine oxide has been determined. All interatomic distances and angles can be considered normal.
Alex J. Veinot   +3 more
doaj   +1 more source

Phosphine-Catalyzed Formal Oxa-[4 + 2] Annulation Employing Nitroethylene and Enones: Enantioselective Synthesis of Dihydropyrans

open access: yes, 2018
The first phosphine-catalyzed enantioselective formal oxa-[4 + 2] reaction between nitroethylene and α-cyano-α,β-unsaturated ketones has been developed.
Zhichao Jin   +9 more
core   +1 more source

Lab‐in‐a‐Tube System Integrating Hierarchically Wrinkled Electrodes and DNAzyme‐Functionalized Beads for Diagnosis of Clostridioides difficile Infection

open access: yesAdvanced Materials, EarlyView.
The point‐of‐care diagnosis of Clostridioides difficile infection remains challenging due to reliance on slow culture and amplification‐based methods. A lab‐in‐a‐tube electrochemical biosensor integrating DNAzymes, antifouling magnetic beads, and a hierarchically structured flow cell enables amplification‐ and culture‐free detection directly in stool ...
Survanshu Saxena   +10 more
wiley   +1 more source

Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine

open access: yesInorganics, 2016
Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine ...
Christine A. Bange   +7 more
doaj   +1 more source

Biochemical Toxic Response of Phosphine on Human Health Estimated From Enzymatic Variance in Trogoderma granarium

open access: yesDose-Response, 2022
The primary purpose of the current study was to study the possible pernicious effects of phosphine gas on enzyme activity alterations in Trogoderma granarium to determine its harmfulness to human beings after its prolonged exposure and intake. The saline
Asma Naeem   +5 more
doaj   +1 more source

Seamless Mechanical Programming Through Hybrid Epoxy–Acrylate Printing for Soft–Rigid Robots

open access: yesAdvanced Materials, EarlyView.
Hybrid epoxy‐acrylate printing enables seamless fabrication of soft–rigid robotic systems with covalently integrated interfaces and functionally graded mechanics. Grayscale exposure expands the accessible material space, enabling spatially programmed actuation through patterned stiffness while revealing the mechanics and durability of continuously ...
David C. Bershadsky   +3 more
wiley   +1 more source

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