Ru single atoms and RuP nanoclusters are co‐anchored in N, P, and B co‐doped porous carbon nanospheres via in situ carbonization/phosphidation of a boronate polymer precursor. RuP activates water, while nearby Ru single atoms accelerate H2 formation through H* transfer. The catalyst delivers low overpotential and high durability in alkaline HER and AEM
Xiaohong Wang +13 more
wiley +1 more source
Reactivity of tri(2-furyl)phosphine (Pfu\u3csub\u3e3\u3c/sub\u3e) with [Mn\u3csub\u3e2\u3c/sub\u3e(CO)\u3csub\u3e10–\u3cem\u3en\u3c/em\u3e\u3c/sub\u3e(NCMe)\u3csub\u3e\u3cem\u3en\u3c/em\u3e\u3c/sub\u3e] (\u3cem\u3en\u3c/em\u3e = 0–2): X-ray Structure of \u3cem\u3emer\u3c/em\u3e-[Mn(CO)\u3csub\u3e3\u3c/sub\u3e(η\u3csup\u3e1\u3c/sup\u3e-C\u3csub\u3e4\u3c/sub\u3eH\u3csub\u3e3\u3c/sub\u3eO)(Pfu\u3csub\u3e3\u3c/sub\u3e)\u3csub\u3e2\u3c/sub\u3e] [PDF]
In the search for new examples of systems that self-assemble into cyclic metal–organic architectures, the six isomers of X,Y′-bis(di(1H-pyrazolyl)methane)-1,1′-biphenyl, LXY, and their silver(I) trifluoromethanesulfonate complexes were prepared.
Ghosh, Shishir +4 more
core +1 more source
Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands [PDF]
A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ = 2,6-diarylphenyl radical) has been prepared and characterized. The stability of these ligands towards oxidation in the air has been
Campos Manzano, Jesús +9 more
core +1 more source
In Situ 3D Bioprinting: Impact of Cross‐Linking on the Adhesive Properties of Hydrogels
In situ 3D bioprinting enables the direct deposition of cell‐laden, adhesive biomaterials for on‐site tissue regeneration. This review provides a comprehensive overview of how cross‐linking influences the bioadhesive properties of hydrogels used in 3D bioprinting, highlighting cross‐linking triggers, bioadhesion mechanisms, polymer interpenetration ...
Odile Romero Fernandez +4 more
wiley +1 more source
Cryptolestes ferrugineus is a serious pest of stored grain and has developed high levels of resistance to phosphine fumigants in many countries. Measuring differences in expression levels of certain ‘resistant’ genes by quantitative real-time PCR (qRT ...
Pei-An Tang +4 more
doaj +1 more source
The lesser grain borer, Rhyzopertha dominica is one of the serious cosmopolitan stored grain pests worldwide. High phosphine resistant R. dominica has been reported in several countries.
Lu, Yujie +4 more
doaj +1 more source
We report a low-temperature colloidal synthesis of WSe2 nanocrystals from tungsten hexacarbonyl and diphenyl diselenide in trioctylphosphine oxide (TOPO).
Jessica Q. Geisenhoff +5 more
doaj +1 more source
Triplet‐Triplet Annihilation Enhances Photochemical Curing Contrast for Vat‐Based 3D Printing
Triplet–triplet annihilation photopolymerization (TTAP) resins enhance curing contrast for digital light processing (DLP) 3D printing compared to conventional Type I and II photopolymerizations at matched optical densities. By exploiting a superlinear initiation response, TTAP preserves fine details, allowing reliable fabrication of complex structures ...
Connor J. O'Dea +2 more
wiley +1 more source
Spectrophotometric studies of the photolysis of diazido-bis(phosphine)-metal(II) complexes [PDF]
The photolysis of mixed ligand complexes of the type MLn(N3)2 (M=Ni, Pd, Pt; L = phosphane and diphosphane ligands, respectively; n = 1, 2) was monitored by electronic spectroscopy in absorption, emission and excitation.
Hennig, H. +3 more
core +1 more source
Meniscus Pixel Printing for Contact‐Lens Vision Sensing and Robotic Control
A visual‐sensing contact lens is enabled by meniscus pixel printing (MPP), which rapidly patterns a 200 µm perovskite photodetector pixel in 1 s without masks, vacuum processing, or bulky equipment. A deep‐learning‐based super‐resolution reconstructs sparse on‐lens signals into 80 × 80 high‐resolution visual information, while AI‐driven eye‐tracking ...
Byung‐Hoon Gong +7 more
wiley +1 more source

