Results 91 to 100 of about 24,914 (301)
Nitroxide‐Mediated Photo‐Polymerization: A Swiss Army Knife for Microfluidic Design
Advanced Materials Technologies, EarlyView.This article illustrates the application of NMP2 to the rapid (less than 1 h) photostructuring and sealing of model structures intended for microfluidic applications. Remarkably, the careful design of resin composition allows completing these steps by simply spreading bare monomer (i.e., no added photoinitiator) on top of the bottom layer embedding ...
Carlo Gonzato +5 more
wiley +1 more source
Frontiers in Chemical BiologyHerein, we present two novel heterobimetallic complexes Ru(II)-Mn(II) (Ru(η6-p-cymene)Cl2PCpMnCl2(H2O)2 (RuPCpMn) and Ru(η6-p-cymene)Cl2PNrMnCl2(H2O)2 (RuPNrMn)) with phosphines (PCp, PNr) derived from fluoroquinolones antibiotics (HCp–ciprofloxacin and ...
Daria Wojtala +10 more
doaj +1 more source
Catalytic Wittig and aza-Wittig reactions
Beilstein Journal of Organic Chemistry, 2016 This review surveys the literature regarding the development of catalytic versions of the Wittig and aza-Wittig reactions. The first section summarizes how arsenic and tellurium-based catalytic Wittig-type reaction systems were developed first due to the
Zhiqi Lao, Patrick H. Toy
doaj +1 more source
Chemoselective Polymerization of Polar Divinyl Monomers with Rare-Earth/Phosphine Lewis Pairs
Molecules, 2018 This work reports the chemoselective polymerization of polar divinyl monomers, including allyl methacrylate (AMA), vinyl methacrylate (VMA), and 4-vinylbenzyl methacrylate (VBMA), by using simple Lewis pairs comprised of homoleptic rare-earth (RE ...
Pengfei Xu, Lei Wu, Liqiu Dong, Xin Xu
doaj +1 more source
Coordination chemistry with phosphine and phosphine oxide-substituted hydroxyferrocenes
Dalton Transactions, 2010 New unsymmetrical hydroxyferrocenes were synthesised from dibromoferrocene. The oxygen heteroatom was introduced via lithiation and quenching with bis-trimethylsilylperoxide followed by hydrolysis to unmask the hydroxyl functionality. The coordination chemistry of 1'-(diphenylphosphino)-1-hydroxyferrocene 2 was explored with palladium and rhodium ...
Atkinson, RCJ +3 more
openaire +4 more sources
Shaping Carbon Nitrides for Advanced Macrostructures
Advanced Materials Technologies, EarlyView.This review examines how carbon nitride can be shaped through a range of printing and interfacial assembly methods. By bringing together additive manufacturing and liquid–liquid structuring concepts, carbon nitride is moving beyond its traditional powder‐based photocatalyst form toward digitally designed robust macroscale architectures with high design
Simona Baluchová, Baris Kumru
wiley +1 more source
Synthesis and Coordination Behavior of a Flexible Bis(phosphinoferrocene) Ligand
Molecules, 2018 A symmetrical flexible bis(phosphinoferrocene) derivative, viz. bis[1′-(diphenylphosphino)ferrocenyl]methane (1), was prepared and studied as a ligand in Pd(II) and Au(I) complexes.
Jiří Schulz +3 more
doaj +1 more source
Reactivity of Gold Hydrides: O2 Insertion into the Au–H Bond [PDF]
, 2015 Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide, (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O2 activation by Au-H in a well-defined system.
Barrio L. +28 more
core +1 more source
3D Printed Omniphobic Slippery Liquid Infused Porous Surfaces for Low Surface Tension Repellency
Advanced Materials Technologies, EarlyView.A 3D printing strategy fabricates omniphobic slippery liquid‐infused porous structures with lubricant reservoirs and interconnected microchannels. A post‐printing surface treatment modifies the porous surface to ensure compatibility with the infused fluorinated lubricant.
Noa Trink, Shlomo Magdassi
wiley +1 more source
Facile Protocol for Water-Tolerant “Frustrated Lewis Pair”-Catalyzed Hydrogenation [PDF]
, 2015 Despite rapid advances in the field of metal-free, “frustrated Lewis pair” (FLP)-catalyzed hydrogenation, the need for strictly anhydrous reaction conditions has hampered wide-scale uptake of this methodology.
Ashley, Andrew E. +5 more
core +3 more sources