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Reduction of secondary and tertiary phosphine oxides to phosphines
Chemical Society Reviews, 2015In this review, we summarise all the methods of phosphine oxide reduction and discuss their mechanistic aspects.
Damien Herault +2 more
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Intramolecular Phosphine−Phosphine Donor−Acceptor Complexes
Inorganic Chemistry, 2009The reaction of 5-diphenoxyphosphanyl-6-diisopropylphosphinoacenaphthene 12 with chlorotrimethylsilane unexpectedly gave a phosphonium-phosphine compound 13, containing the structural motif of four phosphorus atoms connected in a chain. To explain the mechanism of this complex transformation, a proposed intermediate 5-dichlorophosphino-6 ...
Piotr, Wawrzyniak +3 more
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ChemInform, 2009
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Benjamin Schaeffner, Armin Boerner
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Benjamin Schaeffner, Armin Boerner
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Organoplumbyl Phosphines and Phosphine Oxides
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
P. J. Guiry, P. J. McCormack
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Mixed Phosphine—Phosphine Oxide Ligands
ChemInform, 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
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Dioxaphosphabicyclooctanes: small caged phosphines from tris(hydroxymethyl)phosphine
Dalton Transactions, 2023The synthesis and coordination chemistry of sterically small caged phosphines, and their applications as ligands in homogeneous catalysis.
James D. Nobbs +8 more
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Tertiary Amine-Mediated Reductions of Phosphine Oxides to Phosphines
Organic Letters, 2023The reduction of phosphine oxides without the use of highly reactive reductants represents a safer and more sustainable solution for recycling of organophosphorus compounds. Herein, we disclose an N,N,N',N'-tetramethylethylenediamine (TMEDA)-mediated reduction via an unusual intermolecular hydride transfer. Mechanistic studies suggest that TMEDA serves
Keshu Yin +4 more
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Enantioselective Phosphine Organocatalysis
Synlett, 2009The broad potential synthetic usefulness of phosphine-promoted reactions has stimulated many recent investigations on enantioselective variants of known reactions of this family, as well as the search for new, specifically designed, chiral phosphorus catalysts.
Marinetti, A., Voituriez, A.
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Reduction of phosphine oxides to phosphines
Tetrahedron Letters, 2019Abstract The digest is devoted to the most widespread reducing agents which are used for the reduction of tertiary and secondary phosphine oxides, phospholene oxides, phospholane oxides, phosphonates, phosphinates, α- and β-hydroxy and thiomethyl phosphine oxides, α-aminophosphine oxides. Stereoselectivity of reactions is described.
Evgeniya Podyacheva +2 more
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