Results 31 to 40 of about 14,313 (278)
Development of Mononuclear (Arene) Ruthenium Complexes as Anticancer Agents: A Review [PDF]
OUSL Journal, 2022 (Arene)ruthenium complexes have displayed promising activity against cancer and showed fewer side effects compared to platinum-based drugs. Activity tuning of arene complexes have been explored by varying, amines, phosphines and other N^N, N^O, N^S ...
Thilini U. Amarasinghe, Sarath D. Perera
doaj +1 more source
Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes
Inorganics, 2018 The catalytic activity of nickel complexes in hydrophosphination involving secondary phosphines is not a commonly studied transformation. Beyond a small number of stand-out examples, many reports in the literature focus on the use of simple nickel salts.
Ruth L. Webster
doaj +1 more source
, 2018 The synthesis and properties of a series of strongly electron-donating, sterically demanding dialkyl(1,3-diarylimidazolin-2-ylidenamino)phosphines (IAPs) are reported.
Heidar Darmandeh (5714243) +7 more
core +2 more sources
Predicting the Air Stability of Phosphines
DFT calculations form the basis of a model capable of predicting the air stability of phosphines. The sensitivity of 18 primary phosphines is accounted for; the model also predicts the trend of increasing stability from phenylphosphine to ...
Harriman A, Stewart B, Higham LJ
core +5 more sources
Phosphonate–Phosphinate Rearrangement
The Journal of Organic Chemistry, 2015 LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH3O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–phosphonate rearrangement).
Qian, Renzhe +2 more
openaire +2 more sources
Copper(I)-catalyzed asymmetric hydrophosphination of alkenyl azaarenes
Green Synthesis and CatalysisHydrophosphination of α,β-unsaturated carbonyl compounds is one of the most common methods to prepare chiral phosphines. Herein, a copper(I)-catalyzed asymmetric hydrophosphination of alkenyl azaarenes is developed by virtue of the electron-withdrawing ...
Jun-Zhao Xiao +4 more
doaj +1 more source
The Shewanella oneidensis Fic enzyme SoFic targets the switch‐I region of EF‐Tu for AMPylation
FEBS Letters, EarlyView.Fic enzymes mediate diverse post‐translational modifications across all domains of life, including AMPylation. Prokaryotic EF‐Tu can be AMPylated and deAMPylated by the conserved Fic enzyme SoFic. Structural and biochemical approaches were used to characterize the effect of AMPylation on EF‐Tu, SoFic's enzymatic activities, and the enzyme‐target ...
Svenja Runge +6 more
wiley +1 more source
Stoichiometric and Catalytic Synthesis of Alkynylphosphines
Molecules, 2012 Alkynylphosphines or their borane complexes are available either through C–P bond forming reactions or through modification of the phosphorus or the alkynyl function of various alkynyl phosphorus derivatives.
Annie-Claude Gaumont +3 more
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Architecture and synthesis of P,N-heterocyclic phosphine ligands
Beilstein Journal of Organic Chemistry, 2020 Diverse P,N-phosphine ligands reported to date have performed exceptionally well as auxiliary ligands in organometallic catalysis. Phosphines bearing 2-pyridyl moieties prominently feature in literature as compared to phosphines with five-membered N ...
Wisdom A. Munzeiwa +2 more
doaj +1 more source
, 2016 The chiral Pt catalyst precursor Pt((R,R)-Me-Duphos)(Ph)(Cl) mediated alkylation of racemic secondary phosphines PHR(R‘) with benzyl halides in the presence of base to give enantioenriched tertiary phosphines PR(R‘)(CH2Ar).
Corina Scriban (1989502) +1 more
core +1 more source