Results 61 to 70 of about 14,313 (278)

The chemistry of some trifluoromethyl-phosphines

, 1961
One particular aspect of the chemistry of the trifluoromethyl group is its high electron-withdrawing power which reduces the donor properties of normally strong bases. This investigation has been concerned with the chemistry of some phosphines containing
Beg, Mirza Arshad Ali
core   +1 more source

Diversity-oriented synthesis of P-stereogenic and axially chiral monodentate biaryl phosphines enabled by C-P bond cleavage

Nature Communications, 2023
Chiral monodentate biaryl phosphines (MOPs) have attracted intense attention as chiral ligands over the past decades. However, the creation of structurally diverse chiral MOPs with both P- and axial chirality is still in high demand but challenging. Here,
Liangzhi Pang, Zhan Huang, Qilin Sun, Gen Li, Jiaojiao Liu, Baoli Li, Congyue Ma, Jiaxu Guo, Chuanzhi Yao, Jie Yu, Qiankun Li   +10 more
doaj   +1 more source

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

Advanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang, Avirup Sardar, Weijie Ji, Zhongyu Liu, Rongchao Jin   +4 more
wiley   +1 more source

Tetramethylphosphinane as a new secondary phosphine synthon

Communications Chemistry, 2023
Secondary phosphines are important building blocks in organic chemistry as their reactive P—H bond enables construction of more elaborate molecules. In particular, they can be used to construct tertiary phosphines that have widespread applications as ...
James D. Nobbs, Sigit Sugiarto, Xin Yi See, Choon Boon Cheong, Srinivasulu Aitipamula, Ludger P. Stubbs, Martin van Meurs   +6 more
doaj   +1 more source

Soft Yet Tough Tanglemers Through Rapid Photopolymerization for DLP 3D Printing

Advanced Materials, EarlyView.
Soft yet tough tanglemers are produced through low‐initiator free radical photopolymerization and translated to DLP 3D printing. Systematic control over light intensity, initiator loading, and crosslink density reveals processing windows that balance printability, elasticity, toughness, and feature fidelity. ABSTRACT Additive manufacturing of compliant
Yutong Liu, Tiffany N. Jeng, Elizabeth A. Recker, Ellen J. Forehand, Gabriel E. Sanoja, Zachariah A. Page   +5 more
wiley   +1 more source

Introduction of a Phosphine Group onto the Ferrocene Moiety in Ferrociphenol Opens Access to New Heterobimetallic Complexes with Anticancer Activity

ChemistryEurope
Ferrocene analogs of biologically active compounds often exert favorable properties, as demonstrated by ferrocifens derived from the selective estrogen receptor modulator tamoxifen.
Magda Křelinová, Michèle Salmain, Petr Štěpnička, Ivana Císařová, Benoît Bertrand, Jiří Schulz   +5 more
doaj   +1 more source

Predicting the Air Stability of Phosphines

, 2016
DFT calculations form the basis of a model capable of predicting the air stability of phosphines. The sensitivity of 18 primary phosphines is accounted for; the model also predicts the trend of increasing stability from phenylphosphine to ...
Beverly Stewart (2023873), Anthony Harriman (1451335), Lee J. Higham (671005)   +2 more
core   +1 more source

Metastable Polymers for Circular 3D Printing

Advanced Materials, EarlyView.
3D‐printed polymers are usually permanent and hard to recycle. Here, metastable polymers are designed to fall apart on demand. A chemical trigger unzips the printed material back into its original building blocks within minutes at room temperature.
Johannes Markhart, Philipp Mainik, Eva Blasco   +2 more
wiley   +1 more source

Fast Hydrogel Micro‐Actuators Driven by Electric Fields

Advanced Materials, EarlyView.
We report the fabrication of chemically programmable electroactuating microstructures through the first integration of two‐photon polymerization with electrically actuated gelatin methacrylate‐based hydrogels. By tailoring the charge of the polymer network, we demonstrate programmable polarity‐dependent bending, enabling microstructures that ...
Annaël Sort‐Montenegro, Jason M. Delente, Žiga Roblek, Yekaterina Tskhe, Luke Dowling, Colm Delaney, Larisa Florea   +6 more
wiley   +1 more source

Lab‐in‐a‐Tube System Integrating Hierarchically Wrinkled Electrodes and DNAzyme‐Functionalized Beads for Diagnosis of Clostridioides difficile Infection

Advanced Materials, EarlyView.
The point‐of‐care diagnosis of Clostridioides difficile infection remains challenging due to reliance on slow culture and amplification‐based methods. A lab‐in‐a‐tube electrochemical biosensor integrating DNAzymes, antifouling magnetic beads, and a hierarchically structured flow cell enables amplification‐ and culture‐free detection directly in stool ...
Survanshu Saxena, Soyeon Lee, Youngeun Choi, Jonathan L'Heureux‐Hache, Jiaying Liu, Sadman Sakib, Sara M. Imani, Marek Smieja, Yingfu Li, Todd Hoare, Leyla Soleymani   +10 more
wiley   +1 more source