Chiral Phosphoric Acids as Versatile Tools for Organocatalytic Asymmetric Transfer Hydrogenations [PDF]
Herein, recent developments in the field of organocatalytic asymmetric transfer hydrogenation (ATH) of C=N, C=O and C=C double bonds using chiral phosphoric acid catalysis are reviewed.
Adam Mark Palvolgyi +2 more
exaly +3 more sources
H/D Isotope Effects on 1H-NMR Chemical Shifts in Cyclic Heterodimers and Heterotrimers of Phosphinic and Phosphoric Acids [PDF]
Hydrogen-bonded heterocomplexes formed by POOH-containing acids (diphenylphosphoric 1, dimethylphosphoric 2, diphenylphosphinic 3, and dimethylphosphinic 4) are studied by the low-temperature (100 K) 1H-NMR and 31P-NMR using liquefied gases CDF3/CDF2Cl ...
Valeriia V. Mulloyarova +3 more
doaj +2 more sources
Effect of Combined Application of Hydrofluoric and Phosphoric Acids and Active Irrigation with a Microbrush on Shear Bond Strength of Lithium Disilicate Ceramics to Enamel [PDF]
Background: This study assessed the effect of combined application of hydrofluoric (HF) acid and phosphoric acid (PA) and active irrigation (AI) with a microbrush on shear bond strength (SBS) of lithium disilicate (LDS) ceramics to enamel.
Masoud Hatami +2 more
doaj +2 more sources
Chiral 1H NMR of Atropisomeric Quinazolinones With Enantiopure Phosphoric Acids [PDF]
A chiral phosphoric acid promoted enantioselective NMR analysis of atropisomeric quinazolinones was described, in which a variety of racemic arylquinazolinones such as afloqualone and IC-87114 were well recognized with up to 0. 21 ppm ΔΔδ value.
Chaofei Wu +5 more
doaj +2 more sources
Sterically Demanding Flexible Phosphoric Acids for Constructing Efficient and Multi‐Purpose Asymmetric Organocatalysts [PDF]
Fabian Scharinger +2 more
exaly +3 more sources
Are Phosphorous and Phosphoric Acids Equal Phosphorous Sources for Plant Growth?
Phosphorus (P) is one of the 17 elements essential for plant growth and development, and is also a key component in some agrochemicals, such as phosphorous acid. Thus, there are two types of P closely associated with crop production.
Asha M. Brunings +5 more
doaj +7 more sources
Asymmetric Friedel-Crafts Alkylation of Indole with Chalcones Catalyzed by Chiral Phosphoric Acids
The reaction of indole with chalcones, to give Michael-type adducts, was found to occur with good efficiency (up to 98% yield) and moderate enantioselectivity (up to 52% e.e.) in the presence of a chiral BINOL-based phosphoric acid.
Maria Rosaria Acocella +2 more
doaj +3 more sources
Origin of catalytic activity differences between phosphine and phosphine oxide-based structures in the water-crosslinkable polyalkoxysilane composition [PDF]
Organocatalysts have attracted enormous interest in the water-crosslinking reaction in silane-grafted polyolefins (SGPOs) system owing to their simplicity, low toxicity and environmentally benign nature compared to organotin catalysts, which are most ...
Tanaka Shohei, Kenta Adachi
doaj +1 more source
Gas permeable membranes (GPM) are a promising technology for the capture and recovery of ammonia (NH3). The work presented herein assessed the impact of the capture solution and temperature on NH3 recovery for suspended GPM systems, evaluating at a ...
María Soto-Herranz +3 more
doaj +1 more source
Enantioselective Cycloaddition Reactions Catalyzed by BINOL-Derived Phosphoric Acids and N-Triflyl Phosphoramides: Recent Advances [PDF]
Svetlana B Tsogoeva
exaly +2 more sources

