Results 221 to 230 of about 42,123 (288)

Recent Breakthroughs in Cyclizations of <i>Ortho</i>-Quinone Methides. [PDF]

open access: yesMolecules
Wang D   +5 more
europepmc   +1 more source

Ordered Ionic‐Liquid Channels Enable Fast Anhydrous Proton Conduction at up to 240°C for Fuel Cells

open access: yesAngewandte Chemie, EarlyView.
Infiltration of ionic liquids into a composite scaffold comprised of graphene and boron nitride nanosheets functionalised with positively charged polyethyleneimine produces robust proton conducting membranes for the intermediate temperature electrochemical devices.
Mazin Al‐Alawi   +8 more
wiley   +1 more source

Enantioselective Synthesis of Axially Chiral Diaryl Ethers via Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition

open access: yesAngewandte Chemie, EarlyView.
An enantioselective rhodium‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of axially chiral diaryl ethers. Carbonyl coordination ensures high reactivity and regioselectivity, affording products bearing up to four stereogenic axes with good enantio‐ and diastereoselectivity.
Yu Sato   +3 more
wiley   +1 more source

Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries

open access: yesAngewandte Chemie, EarlyView.
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho   +4 more
wiley   +1 more source

Substrate‐Controlled Enantiodivergence in Ni‐Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters

open access: yesAngewandte Chemie, EarlyView.
An efficient, enantiodivergent synthesis of phosphorylated oxindoles with quaternary stereocenters is achieved via a nickel‐catalyzed intermolecular Heck‐phosphorylation cascade. Employing a single chiral catalyst, either product enantiomer is selectively accessed simply by changing the alkene leaving group. DFT calculations trace this stereodivergence
Haimeng Zhu   +4 more
wiley   +1 more source

Catalytic Enantioselective Elimination of Cyclobutanols. [PDF]

open access: yesJ Am Chem Soc
Kumar P   +3 more
europepmc   +1 more source

Catalytic Enantioselective Intramolecular Aza‐Michael Addition to α,β‐Unsaturated Esters

open access: yesAngewandte Chemie, EarlyView.
A general method for accessing enantioenriched saturated N‐heterocycles via a catalytic enantioselective intramolecular aza‐Michael reaction to α,β‐unsaturated esters is described. A superbasic bifunctional iminophosphorane (BIMP) catalyst was key to enabling reactivity of the high pKa sulfonamide pronucleophile, whilst delivering good to excellent ...
Evan G. W. Rutter   +5 more
wiley   +1 more source

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