Results 81 to 90 of about 253,764 (266)

Programmable Functional Silicification of DNA Origami Nanostructures

open access: yesAdvanced Materials, EarlyView.
This work introduces additional functionality into silica‐coated DNA origami nanostructures using non‐standard silica precursors. A fluorescent precursor enables enhanced intracellular tracking, while a disulfide‐containing reagent yields redox‐responsive, degradable silica coatings.
Anna V. Baptist   +4 more
wiley   +1 more source

Electrophilic aryl spiroannulation induced by diaryliodonium salts: efficient synthesis of [5,5]-spiro lactone-lactam scaffolds from α-cyanocarboxylates

open access: yesGreen Synthesis and Catalysis
Spirocyclic architectures represent one of the privileged three-dimensional scaffolds in pharmaceutical chemistry and drug discovery, while the new-skeletal synthesis of spiromolecules from simple starting materials remains a challenging task.
Zhiyuan Bao   +4 more
doaj   +1 more source

Cleavage of the carbon–phosphorus bond in chloromethyl–phosphorus compounds by phosphorus pentachloride [PDF]

open access: yesCanadian Journal of Chemistry, 1968
A novel carbon–phosphorus bond cleavage is described. Chloromethylphosphonic dichloride (2) and bis(chloromethyl)phosphinic chloride (1) both react smoothly and quantitatively with phosphorus pentachloride at 95–100°, giving carbon tetrachloride and a P(III) fragment containing one less carbon–phosphorus bond: phosphorus trichloride from 2 and ...
openaire   +1 more source

Low Resistance Interphase Formation at the PEO‐LiTFSI|LGPS Interface in Lithium Solid‐State Batteries

open access: yesAdvanced Materials Interfaces, EarlyView.
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar   +6 more
wiley   +1 more source

Intra-channel bi-epitopic crosslinking unleashes ultrapotent antibodies targeting NaV1.7 for pain alleviation

open access: yesCell Reports Medicine
Summary: Crucial for cell activities, ion channels are key drug discovery targets. Although small-molecule and peptide modulators dominate ion channel drug discovery, antibodies are emerging as an alternative modality.
Yaning Zhang   +11 more
doaj   +1 more source

Phase Diagrams Enable Solid‐State Battery Design

open access: yesAdvanced Materials Interfaces, EarlyView.
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
wiley   +1 more source

Selective radical-type perfluoro-tert-butylation of unsaturated compounds with a stable and scalable reagent

open access: yesNature Communications
Despite the promising potential of the perfluoro-tert-butyl group in diverse fields such as magnetic resonance imaging, material science and drug design, incorporating this group into organic molecules is still a formidable task, primarily due to its ...
Ruitong Zhang   +8 more
doaj   +1 more source

Measuring and Manipulating Density of States in Two‐Dimensional Materials With Electrochemical Capacitance

open access: yesAdvanced Materials Interfaces, EarlyView.
We report electrochemical quantum capacitance spectroscopy as an ambient, in situ probe for defect‐mediated electronic structure at 2D material interfaces. Using monolayer MoS2, the method resolves band edges and vacancy states, tracks sulfur‐vacancy evolution during hydrogen evolution, and links interfacial density‐of‐states changes to nearly ...
Mengyu Yan   +9 more
wiley   +1 more source

Publisher Correction: Solvent-assisted programming of flat polymer sheets into reconfigurable and self-healing 3D structures

open access: yesNature Communications, 2018
The original version of this Article omitted the Received and Accepted dates; they should have been 21st January 2018 and 12th April 2018, respectively. This has been corrected in the PDF and HTML versions of the Article.
Yang Yang   +3 more
doaj   +1 more source

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