Epigenetic modulators nicotinamide and sodium butyrate reshape the chemical landscape of the endophytic fungus Curvularia sp. G6‐32. Combining the OSMAC strategy with UHPLC‐MS/MS metabolomics and molecular networking reveals a more than twofold rise in treatment‐exclusive metabolites, including diketopiperazines and potentially bioactive natural ...
Guilherme Edison Almeida Pega +8 more
wiley +1 more source
Carbon and Nitrogen Stable Isotopic Discrimination Factors Between Diet and Feces in Wild Giant Pandas. [PDF]
Long G, Wu Y, Huang L, Nie Y, Han H.
europepmc +1 more source
Germylium Catalyzed Dehydrofluorination Reactions of Fluorinated Alkanes
Dehydrofluorination reactions of fluorinated alkanes catalyzed by germylium ions are reported. Computational studies of the mechanism revealed an E2 type mechanism involving a germane as a base to facilitate olefin formation in competition with an SN2 mechanism for hydrodefluorination.
Julie Borel +3 more
wiley +1 more source
Tracking nickel uptake pathways in hyperaccumulator plants using a <sup>61</sup>Ni-enriched stable isotope tracer in soil. [PDF]
Trimmel S +9 more
europepmc +1 more source
Warming and degradation had negligible multi‐year mean effects on annual plant phenology, but their impacts varied strongly with interannual precipitation and spring soil moisture. Degradation amplified warming‐induced advancement of leaf‐out and extended the total active period of the perennial Aster tataricus via microclimatic amplification and ...
Lanying Chen +8 more
wiley +1 more source
Lithium isotope evidence for enhanced continental weathering triggering the late Paleozoic greenhouse-to-icehouse climate transition. [PDF]
Zhang F +10 more
europepmc +1 more source
Ligand Redox Noninnocence in Bis(phosphinimine) Diarylamido Pincer Complexes of Nickel
The oxidative noninnocence of a bis(phosphinimine) ligand featuring a diarylamido backbone was investigated for several nickel complexes. Radical/charge delocalization across the aromatic backbone plays an important role in the stabilization of the diarylaminyl and putative diarylnitrenium complexes.
Xiujing Xing +8 more
wiley +1 more source
A ∼0.5 Myr perturbation of carbon and mercury cycles during the Middle Triassic biotic radiation. [PDF]
Cao Y +15 more
europepmc +1 more source
The inclusion of sulphur at two inorganic nitrogen rates (0 and 150 kg N ha−1) improves plant productivity in a ryegrass–white clover sward and reduces nitrate‐N loss to groundwater in a free‐draining sandy loam soil. ABSTRACT Background Reducing nitrogen (N) losses to water, lessening reliance on inorganic fertiliser and maintaining agricultural ...
Donal Kinsella +2 more
wiley +1 more source
UHRMS Formula Assignment: Diophantine-Based Recalibration Yields Lorentzian Mass Error Distribution as the Limiting Factor. [PDF]
Safaridehkohneh N, Ott A.
europepmc +1 more source

