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Unlocking the Synergistic Promoter Role of Phosphorus in Evolving NiFe Phosphides for Enhanced Water Oxidation [PDF]

open access: yesNano-Micro Letters
Highlights Phosphorus drives NiFeP’s reconstruction into active NiFe (oxy)hydroxide, suppresses Fe dissolution, and modulates Ni’s electronic structure via residual PO4 3−. PO4 3− and Fe synergistically act as a redox buffer, preventing Ni over-oxidation,
Ningning Shi   +11 more
doaj   +2 more sources

Diverse reactivity of the gem-difluorovinyl iodonium salt for direct incorporation of the difluoroethylene group into N- and O-nucleophiles

open access: yesCommunications Chemistry, 2022
The gem-difluoroethylene moiety is considered as a valuable building block in organic synthesis, but methods to introduce it into small molecules are generally limited to specific substrates.
Chenxin Ge   +3 more
doaj   +1 more source

A facile and mild route for the preparation of holey phosphorene by low-temperature electrochemical exfoliation

open access: yesElectrochemistry Communications, 2021
Holey phosphorene, a novel type of nano-black phosphorus, has been theoretically predicted to have potential for a wide range of applications in catalysis, membrane separation and other fields.
Yuncai Jiang   +5 more
doaj   +1 more source

Enabling liquid crystal elastomers with tunable actuation temperature

open access: yesNature Communications, 2023
Liquid crystalline elastomers are regarded as a kind of desirable soft actuator material for soft robotics and other high-tech areas. The isotropization temperature (Ti) plays an important role as it determines the actuation temperature and other ...
Yanjin Yao   +6 more
doaj   +1 more source

Rhodium hydride enabled enantioselective intermolecular C–H silylation to access acyclic stereogenic Si–H

open access: yesNature Communications, 2022
Construction of chiral organosilicon compounds could have implications in photophysical, biological, and chemical fields, as silicon is isoelectronic with carbon, and can mimic carbon atoms while providing slightly different properties.
Kun An   +6 more
doaj   +1 more source

Excellent Electrochemical Performance of Multilayer Graphite Nanosheets as an Anode Material for Lithium-Ion Batteries

open access: yesInternational Journal of Electrochemical Science, 2019
Graphite anodes occupy a considerable share of the commercial market of lithium-ion batteries (LIBs) due to their appropriate potential profile and low cost.
Qiuju Lu   +4 more
doaj   +1 more source

Phosphorus recovery from wastewater by struvite crystallization: A review [PDF]

open access: yes, 2009
The present review provides an understanding of principles of struvite crystallization and examines the techniques and processes experimented to date by researchers at laboratory, pilot, and full-scale to maximize phosphorus removal and reuse as struvite
Hobbs, Phil   +12 more
core   +1 more source

Direct electrophilic and radical isoperfluoropropylation with i-C3F7-Iodine(III) reagent (PFPI reagent)

open access: yesCommunications Chemistry, 2023
The isoperfluoropropyl group (i-C3F7) is an emerging motif in pharmaceuticals, agrichemicals and functional materials. However, isoperfluoropropylated compounds remain largely underexplored, presumably due to the lack of efficient access to these ...
Yaxing Wu   +4 more
doaj   +1 more source

Natural Product-Oriented Photo-Induced Denitrogenative Annulations of 1-Alkenylbenzotriazoles

open access: yesMolecules, 2023
The photo-induced denitrogenative annulations of a variety of 1-alkenylbenzotriazoles were investigated. By judiciously manipulating the structural variations of 1-alkenylbenzotriazoles, two characteristic polycyclic skeletons associated with monoterpene
Zhiguo Wang   +3 more
doaj   +1 more source

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