Results 21 to 30 of about 891,630 (297)

Making and breaking of phosphorus–phosphorus bonds

open access: yesPure and Applied Chemistry, 2018
Abstract In contrast to their mostly unstable isolobal carbon counterparts, oligophosphanide anions, such as M(cyclo-P5 t Bu4) (M=Li, Na) and M2(P4R4) [M=Na, K; R=Ph, t Bu, 2,4,6-Me3C6H2 (Mes)], have unique features, depending on their ...
Toni Grell   +5 more
openaire   +2 more sources

Transition metal complexes of imidazole appended pyridyline linked bisphosphine, 2,6-bis(2-(diphenylphosphanyl)-1H-imidazol-1-yl)pyridine

open access: yesResults in Chemistry, 2021
Large-bite, bisphosphine, 2,6-bis(2-(diphenylphosphanyl)-1H-imidazol-1-yl)-pyridine (BDIP) on treatment with [Mo(NC5H11)2(CO)4], [Ni(PPh3)2(CO)2] and [M(COD)Cl2] [M = Pd, Pt] afforded corresponding chelate complexes [{2,6-{PPh2C3H2N2}2C5H3N}{Mo(CO)4}] (2)
Saurabh Kumar, Maravanji S. Balakrishna
doaj   +1 more source

Characterization of dip effect on strength for gently inclined rock pillar

open access: yesScientific Reports
In underground mining operations, rock pillars play a crucial role as load-bearing elements whose structural integrity exhibits strong correlation with the inclination angle of the ore deposit.
Lijun Sun   +4 more
doaj   +1 more source

Scalable Fabrication of Light-Responsive Superhydrophobic Composite Phase Change Materials via Bionic-Engineered Wood for Solar–Thermal Energy Management

open access: yesMolecules
The growing demand for sustainable energy storage solutions has underscored the importance of phase change materials (PCMs) for thermal energy management. However, traditional PCMs are always inherently constrained by issues such as leakage, poor thermal
Yang Meng   +4 more
doaj   +1 more source

A methionine‐lined active site governs carbocation stabilization and product specificity in a bacterial terpene synthase

open access: yesFEBS Letters, EarlyView.
This study reveals a unique active site enriched in methionine residues and demonstrates that these residues play a critical role by stabilizing carbocation intermediates through novel sulfur–cation interactions. Structure‐guided mutagenesis further revealed variants with significantly altered product profiles, enhancing pseudopterosin formation. These
Marion Ringel   +13 more
wiley   +1 more source

Effect of influent nutrient ratios and hydraulic retention time (HRT) on simultaneous phosphorus and nitrogen removal in a two-sludge sequencing batch reactor process [PDF]

open access: yes, 2009
A laboratory-scale anaerobic–anoxic/nitrification sequencing batch reactor (A2N- SBR) fed with domestic wastewater was operated to examine the effect of varying ratios of influent COD/P, COD/TN and TN/P on the nutrient removal.
Peng, Yongzhen   +2 more
core   +1 more source

dUTPase is essential in zebrafish development and possesses several single‐nucleotide variants with pronounced structural and functional consequences

open access: yesFEBS Open Bio, EarlyView.
dUTPases are involved in balancing the appropriate nucleotide pools. We showed that dUTPase is essential for normal development in zebrafish. The different zebrafish genomes contain several single‐nucleotide variations (SNPs) of the dut gene. One of the dUTPase variants displayed drastically lower protein stability and catalytic efficiency as compared ...
Viktória Perey‐Simon   +6 more
wiley   +1 more source

The potential release of phosphorus in floodplains [PDF]

open access: yes, 2014
In the Illinois River Watershed, there has been growing concern over elevated phosphorus concentrations in the water column. This study evaluated how much phosphorus is contributed from floodplain soils into surface waters, examining the relationship ...
Haggard, Brian E.   +3 more
core   +2 more sources

Synthesis of a Novel Thermoresponsive S53P4 Bioactive Glass Extract–Poloxamer 407 Injectable Hydrogels: Assessment of Biocompatibility and Antimicrobial Properties

open access: yesAdvanced Engineering Materials, EarlyView.
This study investigates innovative thermoreversible hydrogels derived from S53P4 bioactive glass extracts to aid in the healing of infected diabetic foot wounds. These injectable gels, which gel at body temperature, release beneficial ions and remain stable over time.
Marian G. Vargas Guerrero   +9 more
wiley   +1 more source

Exceptional and Anisotropic Transport Properties of Photocarriers in Black Phosphorus

open access: yes, 2015
We show that black phosphorus has room-temperature charge mobilities on the order of 10$^4$ cm$^2$V$^{-1}$s$^{-1}$, which are about one order of magnitude larger than silicon.
Bellus, Matthew Z.   +6 more
core   +2 more sources

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