Results 11 to 20 of about 18,480 (221)
Photocorrosion of WO3 Photoanodes in Different Electrolytes [PDF]
Photocorrosion of an n-type semiconductor is anticipated to be unfavorable if its decomposition potential is situated below its valence band-edge position. Tungsten trioxide (WO3) is generally considered as a stable photoanode for different photoelectrochemical (PEC) applications.
Julius Knöppel +7 more
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Ultrathin Hematite Photoanode with Gradient Ti Doping [PDF]
The poor photoelectrochemical (PEC) performance derived from insufficient charge separation in hematite photoanode crucially limits its application. Gradient doping with band bending in a large region is then considered as a promising strategy, facilitating the charge transfer ability due to the built-in electric field.
Pengfei Liu +5 more
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AbstractAchieving highly performant photoanodes for oxygen evolution is key to developing photoelectrochemical devices for solar water splitting. In this work, BiVO4 photoanodes are enhanced with a series of core–shell structured bimetallic nickel‐cobalt phosphides (MPs), and key insights into the role of co‐catalysts are provided.
Junyi Cui +7 more
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Metal-free photoanodes for C–H functionalization
AbstractOrganic semiconductors, such as carbon nitride, when employed as powders, show attractive photocatalytic properties, but their photoelectrochemical performance suffers from low charge transport capability, charge carrier recombination, and self-oxidation. High film-substrate affinity and well-designed heterojunction structures may address these
Junfang Zhang +8 more
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Controlled Porosity in Ferroelectric BaTiO3 Photoanodes
The use of ferroelectric polarization to promote electron-hole separation has emerged as a promising strategy to improve photocatalytic activity. Although ferroelectric thin films with planar geometry have been largely studied, nanostructured and porous ferroelectric thin films have not been commonly used in photo-electrocatalysis.
Augurio, Adriana +6 more
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Ultrafast Charge Carrier Dynamics in CuWO4 Photoanodes [PDF]
CuWO4 is a ternary metal oxide semiconductor with promising properties for photoelectrochemical (PEC) water splitting and solar light conversion, due to its quite low band gap (2.3 eV) and high stability in an alkaline environment. Aiming at understanding the origin of the relatively low PEC efficiency attained with CuWO4 photoanodes, we here ...
Ivan Grigioni +6 more
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Atomically thin photoanode of InSe/graphene heterostructure [PDF]
AbstractAchieving high-efficiency photoelectrochemical water splitting requires a better understanding of ion kinetics, e.g., diffusion, adsorption and reactions, near the photoelectrode’s surface. However, with macroscopic three-dimensional electrodes, it is often difficult to disentangle the contributions of surface effects to the total photocurrent ...
Haihong Zheng +10 more
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A conductive metal–organic framework photoanode
We report the development of photosensitizing arrays based on conductive metal–organic frameworks (MOFs) that enable light harvesting and efficient charge separation.
Brian Pattengale +7 more
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Photocorrosion Mechanism of TiO2-Coated Photoanodes [PDF]
Atomic layer deposition was used to coat CdS photoanodes with 7 nm thick TiO2films to protect them from photocorrosion during photoelectrochemical water splitting. Photoelectrochemical measurements indicate that the TiO2coating does not provide full protection against photocorrosion.
Didden, A. +3 more
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BiVO4 Ceramic Photoanode with Enhanced Photoelectrochemical Stability [PDF]
Monoclinic bismuth vanadate (BiVO4) is an attractive material with which to fabricate photoanodes due to its suitable band structure and excellent photoelectrochemical (PEC) performance. However, the poor PEC stability originating from its severe photo-corrosion greatly restricts its practical applications.
Zheng, Liren +13 more
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