Porous polymer monoliths embedded with sensitizer–annihilator dye pairs enable efficient solid‐state visible‐to‐ultraviolet triplet–triplet annihilation‐based photon upconversion under low‐intensity blue and green light. Their co‐continuous porous architectures balance chromophore interactions with substrate accessibility, providing robust and tunable ...
Sakura Nakagawa +5 more
wiley +2 more sources
Overcoming the Dexter distance constraint: a relay strategy for asymmetric photocatalysis. [PDF]
Zeng H, Wu J.
europepmc +1 more source
Chirality‐Driven Piezocatalysis in MOFs: Achieving Efficient Cocatalyst‐Free Hydrogen Evolution
We report a chirality‐driven post‐synthetic modification strategy that grafts chiral L‐histidine (L‐His) onto the Hf6 clusters of MOF‐808(Hf), which significantly boosts the piezoelectricity and charge transfer efficiency, thus significantly enhancing the piezocatalytic performance of MOF‐808(Hf).
Yali Ma +7 more
wiley +2 more sources
3D-Printed SiO<sub>2</sub>-BaTiO<sub>3</sub>/SrTiO<sub>3</sub>‑Polymeric Composites for Enhanced Photocatalytic and Piezocatalytic Mitigation of Methylene Blue and Tetracycline Pollutants. [PDF]
Wararam W +11 more
europepmc +1 more source
This study demonstrates that indium clusters with 6s2 lone‐pair effect anchored on carbon nitride act as excitonic electron reservoirs to boost charge separation and O2 activation for highly selective direct 2e− oxygen reduction. This work establishes cluster‐mediated electron reservoir engineering as a general strategy for enhancing selective ...
Shijie Xie +7 more
wiley +2 more sources
Full-Spectrum-Activated Confining Aerogel With Dual-Scale Photothermal Regulation for Ultra-Efficient Low-Temperature Water Purification. [PDF]
Ni J +7 more
europepmc +1 more source
Elucidating Photo‐Kinetic Control in Photothermal Reverse Water‐Gas Shift Reaction
Light directly regulates the rate‐determining step (RDS) in photothermal catalysis. In a Mars–van Krevelen (MvK)‐type reverse water‐gas shift (RWGS) reaction over In‐doped MoO2, light shifts the RDS from the H2‐related reduction half‐reaction to the CO2‐related oxidation half‐reaction, enhancing catalytic activity and lowering the apparent activation ...
Junchuan Sun +13 more
wiley +2 more sources
Silver quantum dots in plasmonic photocatalysis: linking quantum confinement to structure-function relationships. [PDF]
Vasudevan A +8 more
europepmc +1 more source
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri +5 more
wiley +2 more sources
Photoreforming Hydrogen From Polystyrene, Low-Density Polyethylene, and High-Density Polyethylene Microplastics via UV-Driven Photolysis and TiO<sub>2</sub>-Based Photocatalysis. [PDF]
Filip Edelmannová M +5 more
europepmc +1 more source

