Results 181 to 190 of about 68,513 (291)

Monolithic Porous Polymer Architectures for Visible‐to‐UV Upconversion‐Driven Photochemical Reactions

open access: yesAngewandte Chemie, EarlyView.
Porous polymer monoliths embedded with sensitizer–annihilator dye pairs enable efficient solid‐state visible‐to‐ultraviolet triplet–triplet annihilation‐based photon upconversion under low‐intensity blue and green light. Their co‐continuous porous architectures balance chromophore interactions with substrate accessibility, providing robust and tunable ...
Sakura Nakagawa   +5 more
wiley   +2 more sources

Chirality‐Driven Piezocatalysis in MOFs: Achieving Efficient Cocatalyst‐Free Hydrogen Evolution

open access: yesAngewandte Chemie, EarlyView.
We report a chirality‐driven post‐synthetic modification strategy that grafts chiral L‐histidine (L‐His) onto the Hf6 clusters of MOF‐808(Hf), which significantly boosts the piezoelectricity and charge transfer efficiency, thus significantly enhancing the piezocatalytic performance of MOF‐808(Hf).
Yali Ma   +7 more
wiley   +2 more sources

3D-Printed SiO<sub>2</sub>-BaTiO<sub>3</sub>/SrTiO<sub>3</sub>‑Polymeric Composites for Enhanced Photocatalytic and Piezocatalytic Mitigation of Methylene Blue and Tetracycline Pollutants. [PDF]

open access: yesACS Omega
Wararam W   +11 more
europepmc   +1 more source

Indium Clusters With 6s2 Lone‐Pair Effect as Excitonic Electron Reservoirs for Direct 2e− Photocatalytic H2O2 Photosynthesis

open access: yesAngewandte Chemie, EarlyView.
This study demonstrates that indium clusters with 6s2 lone‐pair effect anchored on carbon nitride act as excitonic electron reservoirs to boost charge separation and O2 activation for highly selective direct 2e− oxygen reduction. This work establishes cluster‐mediated electron reservoir engineering as a general strategy for enhancing selective ...
Shijie Xie   +7 more
wiley   +2 more sources

Elucidating Photo‐Kinetic Control in Photothermal Reverse Water‐Gas Shift Reaction

open access: yesAngewandte Chemie, EarlyView.
Light directly regulates the rate‐determining step (RDS) in photothermal catalysis. In a Mars–van Krevelen (MvK)‐type reverse water‐gas shift (RWGS) reaction over In‐doped MoO2, light shifts the RDS from the H2‐related reduction half‐reaction to the CO2‐related oxidation half‐reaction, enhancing catalytic activity and lowering the apparent activation ...
Junchuan Sun   +13 more
wiley   +2 more sources

Silver quantum dots in plasmonic photocatalysis: linking quantum confinement to structure-function relationships. [PDF]

open access: yesRSC Adv
Vasudevan A   +8 more
europepmc   +1 more source

Iron‐Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks

open access: yesAngewandte Chemie, EarlyView.
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri   +5 more
wiley   +2 more sources

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