Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Operando photocatalytic cell for time-resolved XAS/GC analysis of gas phase CO<sub>2</sub> photoreduction. [PDF]
Roth S +7 more
europepmc +1 more source
It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn +4 more
wiley +1 more source
Sustainable photocatalytic removal of cosmetic preservative parabens over a dual S-scheme TiO<sub>2</sub>/ZnO/g-C<sub>3</sub>N<sub>4</sub> catalyst under natural sunlight irradiation. [PDF]
Barik MR, Sarangi A, Badamali SK.
europepmc +1 more source
Decoupling Redox Potentials and Excited State Energies in Substituted Chromium(III) Chromophores
Redox and excited state properties of organic and precious metal CT photocatalysts are strongly entangled. In contrast, redox potentials of polypyridine chromium(III) complexes, that feature purely metal‐centered SF states, are selectively tuned by incremental substituent effects of the CF3 group, while excited state energies and lifetimes remain ...
Steven Sittel +6 more
wiley +1 more source
A Solar-Enabled Strategy for Degrading Allura Red AC Using a Laddered Heterojunction Nanocomposite. [PDF]
Suvarna MY +4 more
europepmc +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
Pechini synthesis and characterization of Co<sub>2</sub>MnO<sub>4</sub> nanostructures and their application as a nano-photocatalyst for degradation of malachite green in contaminated water under sunlight. [PDF]
Yaqoubi M +5 more
europepmc +1 more source
A copper‐catalyzed three‐component radical cascade of 1,5‐enynes with toluene and benzoic acids enables regioselective benzyl radical addition to multi‐Π systems, efficiently delivering polysubstituted indenes from an abundant solvent feedstock. ABSTRACT C─H activation of toluene generates a benzyl radical that undergoes C─C coupling, converting an ...
Saideh Rajai‐Daryasarei +7 more
wiley +1 more source
Visible-light-assisted degradation of crystal violet using CuO- and ZnO-incorporated (Am-<i>co</i>-BA)@PVA hydrogel nanocomposites. [PDF]
Uddin I +4 more
europepmc +1 more source

