Results 201 to 210 of about 59,781 (298)

Modulating Covalent Organic Framework Nanochannel Microenvironments for Sustainable Hydrogen Peroxide Photosynthesis

open access: yesAngewandte Chemie, EarlyView.
Alkoxy side chains regulate hydrazone‐linked COF nanochannel microenvironments by tuning pore polarity, reactant adsorption, and charge‐separation behavior. The optimized framework facilitates oxygen activation and hydrogen peroxide photosynthesis in real water and a 1 L natural‐sunlight reactor. LCA further shows that natural sunlight and larger‐scale
Ruixue Sun   +11 more
wiley   +1 more source

The Nature of Cell‐Penetrating Poly(disulfide)s

open access: yesAngewandte Chemie, EarlyView.
The mode of action of cell‐penetrating poly(disulfide)s (CPDs) is elucidated to understand thiol‐mediated uptake (TMU) in general and guide future efforts to control cellular entry for chemicals delivery and pathogen defense. ABSTRACT Cell‐penetrating poly(disulfide)s (CPDs) are the most popular thiol‐mediated uptake (TMU) tools for delivering attached
Saidbakhrom Saidjalolov   +7 more
wiley   +1 more source

Covalent Organic Framework Colloids With Core‐Shell Donor/Acceptor Architecture and Ultralong‐Lived Charge‐Separated States

open access: yesAngewandte Chemie, EarlyView.
Uniform core‐shell colloidal particles of Covalent Organic Frameworks (COFs) are synthesized by a seeded growth of electron‐acceptor COF shells on electron‐donor COF cores. The resulting p‐n heterojunction enables efficient separation of photogenerated charges, which persist for minutes. These core‐shell COFs show efficient CO2 photoreduction to CO and
Ting Yu   +8 more
wiley   +1 more source

Oxygen‐Tolerant, Controlled Synthesis of Degradable and Water‐Soluble Poly(Vinyl Amide)s via Radical Ring‐Opening Copolymerization of Cyclic Dithiothreitol

open access: yesAngewandte Chemie, EarlyView.
Oxygen‐tolerant photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization enables the controlled radical ring‐opening (rROP) copolymerization of cyclic dithiothreitol (cDTT) with less‐activated vinyl monomers, affording degradable polymers with predictable molecular weights, low dispersities, and ...
Alessandro Magro   +5 more
wiley   +1 more source

Nitrogen Radical Photocatalysed Reduction of Nitrous Oxide

open access: yesAngewandte Chemie, EarlyView.
This work offers the first example of reduction of the potent greenhouse gas N2O to the benign products N2 and O(Bpin)2 using a nitrogen‐based catalyst. The active catalyst is shown to be a nitrogen‐based radical which operates under photocatalytic conditions.
Reece Lister‐Roberts   +2 more
wiley   +1 more source

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