Interfacial charge transfer-driven UV-activated photocatalytic degradation of metronidazole <i>via</i> δ-MnO<sub>2</sub>/WO<sub>3</sub> heterojunction in aqueous media. [PDF]
Islam MS +6 more
europepmc +1 more source
Decoupling Redox Potentials and Excited State Energies in Substituted Chromium(III) Chromophores
Redox and excited state properties of organic and precious metal CT photocatalysts are strongly entangled. In contrast, redox potentials of polypyridine chromium(III) complexes, that feature purely metal‐centered SF states, are selectively tuned by incremental substituent effects of the CF3 group, while excited state energies and lifetimes remain ...
Steven Sittel +6 more
wiley +1 more source
Acridinium amidate as a hydrogen-bonding photocatalyst for direct decarboxylative alkylation of native carboxylic acids. [PDF]
Truong DA +8 more
europepmc +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
Active control of forward/backward charge transfer in Z-scheme water splitting: manipulating electrostatic affinity/repulsion between photocatalyst surface and electron mediator. [PDF]
Itagaki R +4 more
europepmc +1 more source
ABSTRACT The development of synthetic procedures for preparing metal nanoparticles with controlled size using sunlight opens new avenues toward more sustainable methods with lower energy consumption. Herein, we propose the use of double‐vacancy halide perovskites as precursors for engineering highly crystalline and small platinum nanoparticles (< 3 nm)
Kevin Mego +4 more
wiley +1 more source
Construction and Performance Characterization of BiTmFeSbO<sub>7</sub>/BiTmO<sub>3</sub> Heterojunction Photocatalyst and the Photocatalytic Degradation of Sulfathiazole Under Visible Light Irradiation. [PDF]
Luan J, Gou X, Yao Y, Hao L, Ma M.
europepmc +1 more source
Photocatalytic Vanadium‐Mediated Amination of Benzene With Hydroxylamine
Photochemical activation of N‐phenylphenothiazine (PPT) enables a selective direct benzene amination with hydroxylamine in the presence of various vanadium catalysts under mild reaction conditions. Spectroscopic and kinetic analyses identify a key vanadium(IV)‐hydroxylamine intermediate, elucidate the crucial roles of the acidic medium, the ...
Dana Králová +6 more
wiley +1 more source
Visible light-mediated 1,2-difunctionalization reactions involving 4-cyanopyridines. [PDF]
Raymand P +5 more
europepmc +1 more source

