Results 181 to 190 of about 88,628 (298)

Boosting Electron‐Hole Charge Separation in CO2 Photoreduction through Fluoroporphyrin‐Linked Nickel(II)‐Acetylide Frameworks

open access: yesCarbon Energy, EarlyView.
A NiII‐acetylide framework, H2TFPP‐Ni‐AF, demonstrates outstanding photocatalytic CO2 reduction performance: 13.16 mmol h−1 g−1 of CO with 97.9% selectivity. Synergistic interactions, including d‐p orbital hybridization within NiII‐bis(acetylide) moieties ( − C ≡ C−NiII(PBu3)2 − C ≡ C − ) and the efficient charge transport afforded by π‐conjugated ...
Lifen Chen   +6 more
wiley   +1 more source

Superior CO2 Conversion Performance by Er‐Doped BiOCl Nanosheets Through Synergistic Photocatalytic Memory Effect and Er‐Doping

open access: yesCarbon Energy, EarlyView.
Er‐doping and the photocatalytic memory effect through visible‐light irradiation synergistically reconstruct internal electronic states of ultrathin Er‐doped BiOCl nanosheets and generate stable oxygen vacancies. Light absorption, charge carrier separation, and CO2 adsorption capability are subsequently enhanced, leading to a significant increase in ...
Lizhen Lu   +8 more
wiley   +1 more source

Hydrogen Migration Enhances Proton‐Coupled Electron Transfer in an S‐Scheme Heterojunction for High‐Efficiency Photocatalysis

open access: yesCarbon Energy, EarlyView.
Precisely directed built‐in electric field in an S‐scheme heterojunction synergizes photogenerated charge separation with interfacial proton migration, thus co‐localizing electrons and protons on the NOH surface and boosting proton‐coupled electron transfer kinetics in the rate‐determining hydrogen release step. ABSTRACT The kinetic bottleneck in solar‐
Qinhao Zhao   +9 more
wiley   +1 more source

Anodizing for Photocatalysts

open access: yesJournal of The Surface Finishing Society of Japan, 2018
Etsushi TSUJI   +2 more
openaire   +2 more sources

Photothermal CO2 Hydrogenation: Reactions, Mechanisms, and Catalyst Design

open access: yesCarbon Energy, EarlyView.
Reactions, mechanisms, and catalyst design for photothermal CO2 hydrogenation. ABSTRACT Photothermal CO2 hydrogenation has attracted extensive attention because it provides a green and sustainable approach to fuel and chemicals production. The photothermal catalyst plays a critical role in CO2 conversion through a range of reactions.
Shuai Yan   +15 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Photoinduced Electron Transfer (PET) as Key to Accelerate the Cycloreversion Reaction of Arylquadricyclanes

open access: yesChemistry – A European Journal, EarlyView.
It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn   +4 more
wiley   +1 more source

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