Results 181 to 190 of about 47,381 (264)

Direct δ‐Lactone Synthesis From Free Alcohols via Photoinduced δ‐C(sp3)–H Carbonylation in Flow

Angewandte Chemie, EarlyView.
Herein, we have developed a photo‐flow platform for the δ‐C(sp3)─H carbonylative lactonization of free alcohols with carbon monoxide. The transformation integrates alkoxyl radical generation, selective 1,5‐HAT, CO incorporation, and radical–polar crossover to enable direct access to δ‐lactones from simple alcohol precursors.
Prakash Chandra Tiwari, Runkang Liu, Timothy Noël   +2 more
wiley   +1 more source

Enhanced Photocatalytic and Electrical Performance of Boron-Doped ZnO Nanorods: A Taguchi Optimization Approach for Degradation Efficiency. [PDF]

ACS Omega
Tabak E, Öztürk S, Kösemen A, Bayazi̇t ŞS, Kılınç N, Sillanpää M, Benli̇ B.   +6 more
europepmc   +1 more source

Porous Organic Cages for CO2 Capture and Confined Reduction

Angewandte Chemie, EarlyView.
Porous organic cages (POCs) enable the coupling of CO2 capture and conversion through the interplay of molecular structure and solid‐state organization. Beyond intrinsic cavities, packing‐dependent pore accessibility and mass transport govern local CO2 concentration and catalytic performance, linking adsorption to reactivity in integrated capture ...
Valeria Amendola, Sonia La Cognata
wiley   +1 more source

Oxygen-Deficient TiO₂ Aerogel for Enhanced Photocatalytic Performance. [PDF]

Gels
Jiao H, Wang W, Li C, Wang Y, Yuan M, Li Y, Liang D.   +6 more
europepmc   +1 more source

Cage‐Type Porous Organic Salts as Ship‐in‐a‐Bottle Nanoreactors for Light‐Transparent and Reusable Molecular Photocatalysts

Angewandte Chemie, EarlyView.
Light‐transparent, cage‐type porous organic salts (POSs) function as nanoreactors that heterogenize molecularly defined photocatalysts through size exclusion. Photocatalysts are encapsulated intact during crystallization, providing confined yet accessible reaction fields under visible light without catalyst modification.
Kazuki Shiga, Ryosuke Nishikubo, Masafumi Minoshima, Akinori Saeki, Kazuya Kikuchi, Norimitsu Tohnai   +5 more
wiley   +1 more source

Photocatalytic CO₂ reduction to methanol: from mechanistic insights to reactor design integration. [PDF]

RSC Adv
Zuo C, Wang J, Xin C, Su Q.
europepmc   +1 more source

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

Angewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai, Yalei Zhang, Yue Zhao, Shujun Li, Nana Ma, Qingchun Xia, Yiwei Liu, Rongji Liu, Shuxia Liu, Xuenian Chen, Carsten Streb   +10 more
wiley   +1 more source

Fe-Enhanced Proton Capture on Boron Nitride Surfaces for Improved Photocatalytic Methane Conversion to C1 Chemicals. [PDF]

Small Sci
He Y, Yu W, Cao Y, Wang S, Xu K, Zhou Y.
europepmc   +1 more source

Quantitative Photo‐Reforming of Biomass to CO Spurred by In Situ Protonation of Carbon Dioxide Radical Anions

Angewandte Chemie, EarlyView.
A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu, Jinshu Huang, Qizhi Luo, Song Yang, Anders Riisager, Hu Li   +5 more
wiley   +1 more source