SOLiD‐MaP: A Photoproximity Labeling Platform for Small Molecule Binding Site Mapping on RNA
SOLiD‐MaP is a ligand‐directed photoproximity labeling strategy developed for RNA binding‐site analysis. Singlet oxygen‐mediated labeling creates a proximity‐dependent chemical footprint of bound small molecules on RNA. Coupling this chemistry with mutational profiling enables identification of the ligand‐binding region at nucleotide resolution ...
Lin L. Rietveld +4 more
wiley +1 more source
Role of the Character of the Excited State of Singly Reduced Rh<sub>2</sub>(II,II) Intermediates on Photocatalytic Activity. [PDF]
Gupta P, Moore CE, Turro C.
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A metal‐free photocatalytic platform converts nitrones into 4‐isoxazolines and oxa–aza–bicycloheptanes through divergent [3+2π/σ] cycloadditions. Assembly‐controlled kinetic electron transfer gating dictates substrate activation, enabling selective reactivity beyond thermodynamic expectations.
Nayan Saha +6 more
wiley +1 more source
Synthesis and photocatalytic activity of CeO<sub>2</sub>-NbC-x catalysts for degrading oxytetracycline in aquaculture water bodies. [PDF]
Hong F, Gao L.
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Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
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The Photocatalytic Activity of Photoresponsive Silver Nanoparticle/Zinc Oxide Composite Thin Films with Unprecedently Elevated Quantities of Silver. [PDF]
Daniel LS +6 more
europepmc +1 more source
Increasing the density of isolated manganese (Mn) atoms in carbon nitride (CNx) photocatalysts does not continuously improve performance. Instead, beyond a critical loading, the polymer support reorganizes, altering charge‐carrier dynamics and oxygen activation while preserving atomic dispersion.
Viktoria Velichko +14 more
wiley +1 more source
Green synthesis and enhanced photocatalytic activity of ZnSe nanoparticles capped with Artemisia herba-alba and calligonum plants extracts. [PDF]
Alshammari AF +11 more
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A Mild Disilane‐Enabled Halide‐to‐Deuterium Manifold With D2O for Aryl and Benzylic Halides
A broadly applicable Pd‐catalyzed dehalogenative deuteration enables efficient conversion of aryl and benzylic halides with inexpensive deuterium oxide (D2O). The method proceeds under exceptionally mild conditions without strong bases, harsh reductants, or stoichiometric Lewis acid halide scavengers, and tolerates a wide range of functional groups ...
Wenliang Wang +5 more
wiley +1 more source
Construction of Bi<sub>2</sub>MoO<sub>6</sub>/Ag<sub>2</sub>CrO<sub>4</sub> Heterojunction Nanocomposites with Enhanced Visible-Light Photocatalytic Activity and Mechanistic Insight. [PDF]
Hua W, Huang S, Yuan H.
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