Results 211 to 220 of about 125,199 (299)

Bayesian Optimisation for the Experimental Sciences: A Practical Guide to Data‐Efficient Optimisation of Laboratory Workflows

open access: yesAdvanced Intelligent Systems, EarlyView.
This study provides an introduction to Bayesian optimisation targeted for experimentalists. It explains core concepts, surrogate modelling, and acquisition strategies, and addresses common real‐world challenges such as noise, constraints, mixed variables, scalability, and automation.
Chuan He   +2 more
wiley   +1 more source

Oxidation behavior of TiC and TiCN and their potential photocatalytic activity in a semi-oxidized state. [PDF]

open access: yesNanoscale Adv
Tang S   +10 more
europepmc   +1 more source

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

open access: yesAngewandte Chemie, EarlyView.
This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte   +2 more
wiley   +2 more sources

Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor

open access: yesAngewandte Chemie, EarlyView.
Plastic waste is transformed into functional amines via solar‐driven transfer hydrogenation. Soluble monomers from acid hydrolysis of waste polymers serve as a hydrogen (electron/proton)donors in the selective reduction of nitroarenes using a visible light active photocatalyst consisting of cobalt promoted molybdenum disulfide integrated in cyanamide ...
Papa K. Kwarteng   +2 more
wiley   +2 more sources

Visible‐Light Sensitized Isomerization in the Lipid Bilayer Enables Activation of a Transmembrane Transporter

open access: yesAngewandte Chemie, EarlyView.
A stiff‐stilbene‐based transmembrane anion transporter is isomerized by energy transfer from a ruthenium tris(bipyridyl) photosensitizer in the lipid bilayer. This sensitized isomerization allows activation of chloride transport using visible instead of UV light, without the need to chemically modify the stiff‐stilbene photoswitch.
Julia Villalva   +6 more
wiley   +2 more sources

Structure controlled enhanced photocatalytic activity of polyaniline (PANI). [PDF]

open access: yesHeliyon
Rafiq S   +5 more
europepmc   +1 more source

Iron‐Photocatalyzed C(sp3)–H Phosphonylation of Alkanes

open access: yesAngewandte Chemie, EarlyView.
Alkyl phosphonates are valuable motifs that can be prepared by phosphonylations of various common functional groups. However, direct phosphonylations of C(sp3)–H bonds are limited to activated positions. Herein, we report an iron‐photocatalyzed phosphonylation of unactivated C(sp3)–H bonds using a novel phosphite radical trap, which is equipped with an
Ya Dong   +6 more
wiley   +2 more sources

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